N1501
新亚铜试剂
≥98%
别名:
2,9-二甲基-1,10-菲咯啉, DMPHEN
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关于此项目
经验公式（希尔记法）:
C14H12N2
化学文摘社编号:
分子量:
208.26
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
207-601-9
MDL number:
Assay:
≥98%
Form:
crystalline
Quality Level
assay
≥98%
form
crystalline
color
white to beige
SMILES string
Cc1ccc2ccc3ccc(C)nc3c2n1
InChI
1S/C14H12N2/c1-9-3-5-11-7-8-12-6-4-10(2)16-14(12)13(11)15-9/h3-8H,1-2H3
InChI key
IYRGXJIJGHOCFS-UHFFFAOYSA-N
General description
新铜试剂是一种杂环有机化合物。常作为螯合剂，用于各种过渡金属催化的反应。包括醇氧化反应、碳碳键的氧化断裂反应、碳碳键形成的偶联反应、羰基化合物的烯丙基化反应、烷基锌炔基化反应、镍介导的脱羰交叉偶联反应、Buchwald–Hartwig偶联反应和烯丙基取代反应。
Application
新铜试剂可作为配体，用于：
- 制备氟化金属-有机框架材料(F-MOFs)。
- 吲哚类和苯基硼酸类通过氧化硼Heck反应实现区域选择性C-H芳基化。
- Zn(OH)2为催化剂，醛和烯丙基硼酸酯的烯丙基化反应。
- 五元杂环芳烃经由铱催化的硅烷化反应合成硅基芳烃。
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存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Assem Barakat et al.
International journal of molecular sciences, 14(12), 23941-23954 (2013-12-20)
[NiCl2(C14H12N2)(H2O)] complex has been synthesized from nickel chloride hexahydrate (NiCl2·6H2O) and 2,9-dimethyl-1,10-phenanthroline (dmphen) as N,N-bidentate ligand. The synthesized complex was characterized by elemental analysis, infrared (IR) spectroscopy, ultraviolet-visible (UV-vis) spectroscopy and differential thermal/thermogravimetric analysis (TG/DTA). The complex was further confirmed
Shū Kobayashi et al.
Chemistry, an Asian journal, 8(9), 2033-2045 (2013-06-19)
Zn(OH)2-catalyzed allylation reactions of aldehydes with allylboronates in aqueous media have been developed. In contrast to conventional allylboration reactions of aldehydes in organic solvents, the α-addition products were obtained exclusively. A catalytic cycle in which the allylzinc species was generated
Yan Wang et al.
Journal of the American Society for Mass Spectrometry, 19(9), 1353-1360 (2008-07-19)
S-nitrosylation of proteins serves an important role in regulating diverse cellular processes including signal transduction, DNA repair, and neurotransmission. Identification of S-nitrosylation sites is crucial for understanding the significance of this post-translational modification (PTM) in modulating the function of a
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| N1501-5G | 04061834109426 |
| N1501-1G | 04061834109341 |
| N1501-25G | 04061834109389 |