质量水平
方案
≥98%
表单
crystalline
颜色
white to beige
SMILES字符串
Cc1ccc2ccc3ccc(C)nc3c2n1
InChI
1S/C14H12N2/c1-9-3-5-11-7-8-12-6-4-10(2)16-14(12)13(11)15-9/h3-8H,1-2H3
InChI key
IYRGXJIJGHOCFS-UHFFFAOYSA-N
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一般描述
新铜试剂是一种杂环有机化合物。常作为螯合剂，用于各种过渡金属催化的反应。包括醇氧化反应、碳碳键的氧化断裂反应、碳碳键形成的偶联反应、羰基化合物的烯丙基化反应、烷基锌炔基化反应、镍介导的脱羰交叉偶联反应、Buchwald–Hartwig偶联反应和烯丙基取代反应。
应用
新铜试剂可作为配体，用于：
- 制备氟化金属-有机框架材料(F-MOFs)。
- 吲哚类和苯基硼酸类通过氧化硼Heck反应实现区域选择性C-H芳基化。
- Zn(OH)2为催化剂，醛和烯丙基硼酸酯的烯丙基化反应。
- 五元杂环芳烃经由铱催化的硅烷化反应合成硅基芳烃。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Shū Kobayashi et al.
Chemistry, an Asian journal, 8(9), 2033-2045 (2013-06-19)
Zn(OH)2-catalyzed allylation reactions of aldehydes with allylboronates in aqueous media have been developed. In contrast to conventional allylboration reactions of aldehydes in organic solvents, the α-addition products were obtained exclusively. A catalytic cycle in which the allylzinc species was generated
Assem Barakat et al.
International journal of molecular sciences, 14(12), 23941-23954 (2013-12-20)
[NiCl2(C14H12N2)(H2O)] complex has been synthesized from nickel chloride hexahydrate (NiCl2·6H2O) and 2,9-dimethyl-1,10-phenanthroline (dmphen) as N,N-bidentate ligand. The synthesized complex was characterized by elemental analysis, infrared (IR) spectroscopy, ultraviolet-visible (UV-vis) spectroscopy and differential thermal/thermogravimetric analysis (TG/DTA). The complex was further confirmed
Yan Wang et al.
Journal of the American Society for Mass Spectrometry, 19(9), 1353-1360 (2008-07-19)
S-nitrosylation of proteins serves an important role in regulating diverse cellular processes including signal transduction, DNA repair, and neurotransmission. Identification of S-nitrosylation sites is crucial for understanding the significance of this post-translational modification (PTM) in modulating the function of a
Saliha Esin Celik et al.
Analytica chimica acta, 674(1), 79-88 (2010-07-20)
A novel on-line HPLC-cupric reducing antioxidant capacity (CUPRAC) method was developed for the selective determination of polyphenols (flavonoids, simple phenolic and hydroxycinnamic acids) in complex plant matrices. The method combines chromatographic separation, constituent analysis, and post-column identification of antioxidants in
Mustafa Ozyürek et al.
Analytica chimica acta, 616(2), 196-206 (2008-05-17)
Hydroxyl radicals (OH) generated in the human body may play an important role in tissue injury at sites of inflammation in oxidative stress-originated diseases. As a more convenient, efficient, and less costly alternative to HPLC/electrochemical detection techniques and to the
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