N1909
1-萘甲酸
96%
别名:
1-萘酸
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线性分子式:
C10H7CO2H
化学文摘社编号:
分子量:
172.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-681-9
Beilstein/REAXYS Number:
1908896
MDL number:
产品名称
1-萘甲酸, 96%
InChI
1S/C11H8O2/c12-11(13)10-7-3-5-8-4-1-2-6-9(8)10/h1-7H,(H,12,13)
InChI key
LNETULKMXZVUST-UHFFFAOYSA-N
SMILES string
OC(=O)c1cccc2ccccc12
assay
96%
form
powder
bp
300 °C (lit.)
mp
157-160 °C (lit.)
Quality Level
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Application
1-萘甲酸可作为以下应用的反应剂：
- 在铑催化剂存在下，与炔烃通过脱水环化反应制备萘嵌苯酮。
- 使用Rh催化剂，与2-丁炔通过有氧的氧化环化反应制备异香豆素衍生物。
- 与N,O-二甲基羟胺和三氯化磷反应制备N-甲氧基-N-甲基-1-萘甲酰胺（Weinreb酰胺）。
- 通过Birch还原反应制备1,4-二氢-1-萘羧酸。
Other Notes
残留物为 2-萘甲酸
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Josef B G Gluyas et al.
Organic & biomolecular chemistry, 10(34), 6914-6929 (2012-07-21)
Silicon chemistry offers the potential to tune the effects of biologically active organic molecules. Subtle changes in the molecular backbone caused by the exchange of a carbon atom for a silicon atom (sila-substitution) can significantly alter the biological properties. In
Mutual activation: Suzuki-Miyaura coupling through direct cleavage of the sp2 C-O bond of naphtholate.
Da-Gang Yu et al.
Angewandte Chemie (International ed. in English), 50(31), 7097-7100 (2011-06-29)
S Chandra et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 74(3), 704-713 (2009-09-02)
The Fourier transform infrared gas phase spectrum of Naphthoic acid (NA) was recorded in the region 4000-400 cm(-1). The Fourier transform Raman spectrum and Fourier transform IR spectra of NA were recorded in solid phase. Quantum chemical calculations of energies
Qunfei Zhao et al.
Chemistry & biology, 15(7), 693-705 (2008-07-19)
Azinomycin B is a complex natural product containing densely assembled functionalities with potent antitumor activity. Cloning and sequence analysis of the azi gene cluster revealed an iterative type I polyketide synthase (PKS) gene, five nonribosomal peptide synthetases (NRPSs) genes and
Hiromasa Uchiyama et al.
European journal of pharmaceutical sciences : official journal of the European Federation for Pharmaceutical Sciences, 43(1-2), 71-77 (2011-04-06)
Spray-dried particles (SDPs) with indomethacin (IND) and alpha-glycosyl transferase-treated stevia (Stevia-G) indicated extremely high dissolution rates and apparent solubility compared to particles of a ground mixture and a physical mixture of IND/Stevia-G. The apparent solubility of IND from SDPs was
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