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Merck
CN

P27127

Sigma-Aldrich

醋酸苯汞

97%

别名:

醋酸苯汞, 乙酸苯汞

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线性分子式:
C6H5HgOCOCH3
化学文摘社编号:
分子量:
336.74
Beilstein:
3662930
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

97%

表单

powder

mp

148-151 °C (lit.)

SMILES字符串

CC(=O)O[Hg]c1ccccc1

InChI

1S/C6H5.C2H4O2.Hg/c1-2-4-6-5-3-1;1-2(3)4;/h1-5H;1H3,(H,3,4);/q;;+1/p-1

InChI key

XEBWQGVWTUSTLN-UHFFFAOYSA-M

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应用

乙酸苯汞(PMA)可以与钯盐(例如乙酸钯)在原位反应形成芳基钯盐,然后与伯或仲烯丙醇反应生成3-芳基醛。也可用于经Floyd′s途径多步合成2,3,4,6-四-O-乙酰基-α-D-吡喃葡萄糖基硫醇。

免责声明

对于美国客户:本品含汞。废弃后切勿放入垃圾桶,须按照地方、州或联邦法律处置。

警示用语:

Danger

危险分类

Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 1

靶器官

Kidney,Central nervous system

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The arylation of allylic alcohols with organopalladium compounds. A new synthesis of 3-aryl aldehydes and ketones.
Heck R F, et al.
Journal of the American Chemical Society, 90(20), 5526-5531 (1968)
Synthesis of aromatic and indole alpha-glucosinolates.
Vo Quan V, et al.
Carbohydrate Research, 455, 45-53 (2018)
Satu Lyyra et al.
Plant biotechnology journal, 5(2), 254-262 (2007-02-21)
Eastern cottonwood (Populus deltoides Bartr. ex Marsh.) trees were engineered to express merA (mercuric ion reductase) and merB (organomercury lyase) transgenes in order to be used for the phytoremediation of mercury-contaminated soils. Earlier studies with Arabidopsis thaliana and Nicotiana tabacum
S K Ghosh et al.
Journal of applied microbiology, 102(2), 375-383 (2007-01-24)
Mercury compounds are highly toxic to all types of living cells. Isolated yeast strains of Rhodotorula rubra showed high and low resistance pattern towards mercury and organomercurial compounds. To investigate the basis of differential sensitivity of these two types of
Harry J Beaulieu et al.
Journal of occupational and environmental hygiene, 5(6), 360-366 (2008-03-28)
Phenyl mercuric acetate (PMA) historically has been used as a catalyst in polyurethane systems. In the 1950s-1970s, PMA was used as a catalyst in the 3M Tartan brand polyurethane flexible floors that were installed commonly in school gymnasiums. Mercury vapor

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