所有图片(3)

文件

P28808

苯基次膦酸

Name: 苯基次膦酸
Brand: ALDRICH

99%

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所有图片(3)

线性分子式:

C₆H₅P(O)(OH)H

CAS号:

1779-48-2

分子量:

142.09

Beilstein:

2802244

EC 号:

217-217-3

MDL编号:

MFCD00002131

PubChem化学物质编号:

24898369

质量水平

200

检测方案

99%

形式

powder

mp

83-85 °C (lit.)

SMILES string

O[PH](=O)c1ccccc1

InChI

1S/C6H7O2P/c7-9(8)6-4-2-1-3-5-6/h1-5,9H,(H,7,8)

InChI key

MLCHBQKMVKNBOV-UHFFFAOYSA-N

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一般描述

苯基膦酸又名苯膦酸。研究了用金属和非金属氧化剂氧化苯基次膦酸这一过程的动力学。2

象形图

GHS05,GHS07

警示用语：

Danger

危险声明

H302 - H314

预防措施声明

P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

危险分类

Acute Tox. 4 Oral - Skin Corr. 1B

储存分类代码

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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示例

T1503

货号

25G

包装规格/数量

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705578-5MG-PW

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MMYOMAG-74K-13

1000309185

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First principles NMR calculations of phenylphosphinic acid C6H5HPO(OH): assignments, orientation of tensors by local field experiments and effect of molecular motion.

C Gervais et al.

Journal of magnetic resonance (San Diego, Calif. : 1997), 187(1), 131-140 (2007-05-08)

The complete set of NMR parameters for (17)O enriched phenylphosphinic acid C(6)H(5)HP( *)O(*OH) is calculated from first principles by using the Gauge Including Projected Augmented Wave (GIPAW) approach [C.J. Pickard, F. Mauri, All-electron magnetic response with pseudopotentials: NMR chemical shifts

Four week feeding toxicity study with phenylphosphinic acid in rats.

E Maria Donner et al.

Drug and chemical toxicology, 26(2), 125-133 (2003-06-21)

Phenylphosphinic acid was fed in graded concentrations of either 0 (control), 100, 1,000, or 10,000 ppm to rats for 28 days. These concentrations provided average daily doses of 8, 76, and 779 mg/kg (males) and 9, 83, and 859 mg/kg

Photophysical and structural impact of phosphorylated anions associated to lanthanide complexes in water.

Loïc J Charbonnière et al.

Inorganic chemistry, 44(20), 7151-7160 (2005-09-27)

A new ligand, LC, bis-[(6'-carboxy-2,2'-bipyridine-6-yl)]phenylphosphine oxide, in which the tridentate 6-carboxy-2,2'-bipyridyl arms are directly linked to a phenylphosphine oxide fragment, has been synthesized. The corresponding [Ln.LC]Cl.xH2O complexes (Ln = Eu, x = 4, and Tb, x = 3) were isolated

Design of a new dental adhesive--effect of a water-soluble sodium acylphosphine oxide with crown ether on adhesion to dental hard tissues.

Kunio Ikemura et al.

Dental materials journal, 28(3), 267-276 (2009-08-11)

The behavior of water-soluble photoinitiators with crown ethers in dental adhesives is unknown. This study investigated the effect of sodium acylphosphine oxide (APO-Na) with crown ether in a hydrophobic adhesive on adhesion to teeth. Sodium 2,4,6-trimethylbenzoyl-phenylphosphine oxide (TMPO-Na = APO-Na)

Stereospecific addition of H-P bond to alkenes: a simple method for the preparation of (R(P))-phenylphosphinates.

Li-Biao Han et al.

The Journal of organic chemistry, 70(24), 10121-10123 (2005-11-19)

[reaction: see text] A variety of functionalized optically pure (R(P))-alkylphenylphosphinates are readily prepared by stereospecific radical or base-catalyzed additions of the easily available (R(P))-menthyl phenylphosphinate to alkenes.

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