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Merck
CN

P29006

苯膦酸

98%

别名:

Benzene phosphonic acid

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关于此项目

线性分子式:
C6H5P(O)(OH)2
化学文摘社编号:
分子量:
158.09
UNSPSC Code:
12352300
NACRES:
NA.23
PubChem Substance ID:
EC Number:
216-388-1
Beilstein/REAXYS Number:
2245168
MDL number:
Assay:
98%
Form:
crystals
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InChI key

QLZHNIAADXEJJP-UHFFFAOYSA-N

InChI

1S/C6H7O3P/c7-10(8,9)6-4-2-1-3-5-6/h1-5H,(H2,7,8,9)

SMILES string

OP(O)(=O)c1ccccc1

assay

98%

form

crystals

Quality Level

mp

162-164 °C (lit.)

Application

与 Noyori 催化剂配合使用,用于将硫化物氧化为砜类的添加剂。

Noyori 氧化(二水合钨酸钠、过氧化氢、甲基三正辛基硫酸氢铵、磷酸)
苯基膦酸的自组装单分子膜 (SAMs) 可用于制备有机半导体与透明导电氧化物之间的界面。酸可用于使二氧化钛颗粒功能化。与 Noyor® 催化剂配合使用,用于硫化物绿色氧化为砜。

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Justin L Ford et al.
Helicobacter, 12(6), 609-615 (2007-11-16)
Helicobacter pylori can utilize phenylphosphonate as a sole source of phosphorus, and it is able to transport the phosphonate N-phosphonoacetyl-L-aspartate. However, H. pylori does not have any genes homologous to those of the known pathways for phosphonate degradation in bacteria
Important reaction parameters in the synthesis of phenylphosphonic acid functionalized titania particles by reactive milling.
Betke A and Kickelbick G
New. J. Chem., 38(3), 1264-1270 (2014)
T Q Duong et al.
Magnetic resonance in medicine, 45(5), 801-810 (2001-04-27)
The apparent diffusion coefficients (ADCs) of a series of markers concentrated in the extracellular space of normal rat brain were measured to evaluate, by inference, the ADC of water in the extracellular space. The markers (mannitol, phenylphosphonate, and polyethylene glycols)
Orientation of Phenylphosphonic Acid Self-Assembled Monolayers on a Transparent Conductive Oxide: A Combined NEXAFS, PM-IRRAS, and DFT Study
Gliboff M, et al.
Langmuir, 29(7), 2166?2174-2166?2174 (2013)
K Hendrich et al.
Journal of magnetic resonance. Series B, 105(3), 225-232 (1994-11-01)
Spatial localization with the spectroscopic imaging technique is normally implemented with the Fourier-transform approach, yielding rectangular voxels, with potentially significant cross-voxel contamination. Multidimensional Fourier-series window (FSW) is an alternate approach that generates single voxels of predetermined shape, with minimal out-of-voxel

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