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Merck
CN

P35405

Sigma-Aldrich

二苯基亚砜

96%

别名:

苯基亚砜

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关于此项目

线性分子式:
(C6H5)2SO
化学文摘社编号:
分子量:
202.27
Beilstein:
1908444
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

96%

表单

crystals

沸点

206-208 °C/13 mmHg (lit.)

mp

69-71 °C (lit.)

SMILES字符串

O=S(c1ccccc1)c2ccccc2

InChI

1S/C12H10OS/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H

InChI key

JJHHIJFTHRNPIK-UHFFFAOYSA-N

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应用

  • 制备放射性化合物:在由 [(11)C]碘甲烷合成[(11)C]氰化物的过程中二苯亚砜起一定作用Kikuchi et al., 2022)。
  • 催化氧化过程:考察了二苯基硫的光催化和催化氧化形成亚砜的过程,重点介绍了过氧化氢和TiO2 多形体(polymorph)在优化化学过程中的有效性(Mikrut et al., 2022)。
  • 电介质性质研究:有关高有机硫煤的电介质性质研究重点关注了硫化合物(包括二苯亚砜)的改造,增进了我们对材料科学能量领域的理解(Cai et al., 2019)。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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S C Mitchell et al.
Xenobiotica; the fate of foreign compounds in biological systems, 28(7), 715-722 (1998-08-26)
1. Radiolabelled diphenyl sulphoxide (U-14C- or 35S-) was administered by gavage (1.0 mmol/kg body weight) to the adult male Wistar rat following an overnight fast. 2. For both labelled forms faeces was the major route of excretion of radioactivity (50%)
Lu Liu et al.
Chemical reviews, 119(24), 12422-12490 (2019-12-14)
More than 50 years have passed since Haszeldine reported the first addition of a trifluoromethyl radical to an allene; in the intervening years, both the chemistry of allenes and the reactivity of single-electron species have become topics of intense interest.
S C Lee et al.
Biochemical pharmacology, 49(11), 1557-1565 (1995-05-26)
The reduction of sulindac, sulphinpyrazone and diphenyl sulphoxide to their thioether analogues has been studied in vitro using rat and rabbit tissues. Sulindac reduction was about 10-fold higher in homogenates of rat kidney and liver than in other tissues although
S C Lee et al.
Biochemical pharmacology, 49(11), 1567-1576 (1995-05-26)
The caecal microflora from female rats show a greater ability to reduce the sulphoxide group of sulindac than either the liver or kidneys. Studies on sulphoxide reduction by Escherichia coli showed that NADH, NADPH and dithiothreitol (DTT), but not acetaldehyde
Deju Ye et al.
The Journal of organic chemistry, 74(4), 1733-1735 (2009-01-20)
An efficient approach to the dehydrative sialylation of various substrates with C-4-aminated sialyl-hemiketal donors by using the reagent combination of diphenyl sulfoxide and triflic anhydride is reported. By using a C-4-hindered non-nucleophilic amine auxiliary, excellent yields and high alpha-stereoselectivities were

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