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Merck
CN

P35405

二苯基亚砜

96%

别名:

苯基亚砜

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关于此项目

线性分子式:
(C6H5)2SO
化学文摘社编号:
分子量:
202.27
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-415-9
Beilstein/REAXYS Number:
1908444
MDL number:
Assay:
96%
Form:
crystals
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Quality Level

assay

96%

form

crystals

bp

206-208 °C/13 mmHg (lit.)

mp

69-71 °C (lit.)

SMILES string

O=S(c1ccccc1)c2ccccc2

InChI

1S/C12H10OS/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H

InChI key

JJHHIJFTHRNPIK-UHFFFAOYSA-N

Application

  • 制备放射性化合物:在由 [(11)C]碘甲烷合成[(11)C]氰化物的过程中二苯亚砜起一定作用Kikuchi et al., 2022)。
  • 催化氧化过程:考察了二苯基硫的光催化和催化氧化形成亚砜的过程,重点介绍了过氧化氢和TiO2 多形体(polymorph)在优化化学过程中的有效性(Mikrut et al., 2022)。
  • 电介质性质研究:有关高有机硫煤的电介质性质研究重点关注了硫化合物(包括二苯亚砜)的改造,增进了我们对材料科学能量领域的理解(Cai et al., 2019)。


存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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David Crich et al.
Organic letters, 8(5), 959-962 (2006-02-24)
The formation of sialic acid glycosides with a thiosialic acid derivative, diphenyl sulfoxide, and trifluoromethanesulfonic anhydride is reported. With an excess of diphenyl sulfoxide, glycal formation can be completely suppressed and excellent yields are obtained for coupling to a wide
S C Lee et al.
Biochemical pharmacology, 49(11), 1567-1576 (1995-05-26)
The caecal microflora from female rats show a greater ability to reduce the sulphoxide group of sulindac than either the liver or kidneys. Studies on sulphoxide reduction by Escherichia coli showed that NADH, NADPH and dithiothreitol (DTT), but not acetaldehyde
Deju Ye et al.
The Journal of organic chemistry, 74(4), 1733-1735 (2009-01-20)
An efficient approach to the dehydrative sialylation of various substrates with C-4-aminated sialyl-hemiketal donors by using the reagent combination of diphenyl sulfoxide and triflic anhydride is reported. By using a C-4-hindered non-nucleophilic amine auxiliary, excellent yields and high alpha-stereoselectivities were



全球贸易项目编号

货号GTIN
P35405-100G04061834368175
P35405-25G04061834368182