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P35405

二苯基亚砜

96%

别名:

苯基亚砜

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关于此项目

线性分子式:
(C6H5)2SO
化学文摘社编号:
945-51-7
分子量:
202.27
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24898426
EC Number:
213-415-9
Beilstein/REAXYS Number:
1908444
MDL number:
MFCD00002085
Assay:
96%
Form:
crystals
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Quality Level

100

assay

96%

form

crystals

bp

206-208 °C/13 mmHg (lit.)

mp

69-71 °C (lit.)

SMILES string

O=S(c1ccccc1)c2ccccc2

InChI

1S/C12H10OS/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H

InChI key

JJHHIJFTHRNPIK-UHFFFAOYSA-N

Application

  • 制备放射性化合物：在由 [（11）C]碘甲烷合成[（11）C]氰化物的过程中二苯亚砜起一定作用Kikuchi et al., 2022）。
  • 催化氧化过程：考察了二苯基硫的光催化和催化氧化形成亚砜的过程，重点介绍了过氧化氢和TiO2 多形体（polymorph）在优化化学过程中的有效性（Mikrut et al., 2022）。
  • 电介质性质研究：有关高有机硫煤的电介质性质研究重点关注了硫化合物（包括二苯亚砜）的改造，增进了我们对材料科学能量领域的理解（Cai et al., 2019）。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB8261
SDBB7790
SDBB3701
SDBB2495
STBL3283

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Martin A Fascione et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(10), 2987-2997 (2012-02-02)
Sulfoxides are frequently used in organic synthesis as chiral auxiliaries and reagents to mediate a wide variety of chemical transformations. For example, diphenyl sulfoxide and triflic anhydride can be used to activate a wide range of glycosyl donors including hemiacetals
S Yoshihara et al.
Drug metabolism and disposition: the biological fate of chemicals, 18(6), 876-881 (1990-11-01)
To evaluate the metabolic capacity of intact guinea pig liver under normoxic and hypoxic conditions, oxidative and reductive metabolism of diphenyl sulfoxide (DPSO) was studied by the nonrecirculating perfusion method in situ. DPSO was exclusively converted into diphenyl sulfone (DPSO2)
J A Kozlowski et al.
Bioorganic & medicinal chemistry letters, 10(20), 2255-2257 (2000-10-31)
Structure activity studies on [4-(phenylsulfonyl)phenyl]methylpiperazine led to the discovery of 4-cyclohexyl-alpha-[4-[[4-methoxyphenyl(S)-sufinyl]phenyl]-1-pi perazineacetonitrile, 1, an M2 selective muscarinic antagonist. Affinity at the cloned human M2 receptor was 2.7 nM; the M1/M2 selectivity is 40-fold.
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全球贸易项目编号

货号GTIN
P35405-25G04061834368182
P35405-100G04061834368175