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Merck
CN

P35405

二苯基亚砜

96%

别名:

苯基亚砜

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关于此项目

线性分子式:
(C6H5)2SO
化学文摘社编号:
分子量:
202.27
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-415-9
Beilstein/REAXYS Number:
1908444
MDL number:
Assay:
96%
Form:
crystals
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InChI key

JJHHIJFTHRNPIK-UHFFFAOYSA-N

InChI

1S/C12H10OS/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H

SMILES string

O=S(c1ccccc1)c2ccccc2

assay

96%

form

crystals

bp

206-208 °C/13 mmHg (lit.)

mp

69-71 °C (lit.)

Quality Level

Application

  • 制备放射性化合物:在由 [(11)C]碘甲烷合成[(11)C]氰化物的过程中二苯亚砜起一定作用Kikuchi et al., 2022)。
  • 催化氧化过程:考察了二苯基硫的光催化和催化氧化形成亚砜的过程,重点介绍了过氧化氢和TiO2 多形体(polymorph)在优化化学过程中的有效性(Mikrut et al., 2022)。
  • 电介质性质研究:有关高有机硫煤的电介质性质研究重点关注了硫化合物(包括二苯亚砜)的改造,增进了我们对材料科学能量领域的理解(Cai et al., 2019)。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Wen-Xian Li et al.
Luminescence : the journal of biological and chemical luminescence, 26(6), 754-761 (2011-05-14)
A novel ternary complex, TbL(5) L'(ClO(4))(3) · 3H(2)O, two binary complexes, TbL(7) (ClO(4))(3) · 3H(2)O and TbL'(3.5) (ClO(4))(3) · 4H(2)O has been synthesized (using diphenyl sulphoxide as the first ligand L, bipyridine as the second ligand L'). Their composition was
Tomofumi Takuwa et al.
Chemical & pharmaceutical bulletin, 53(5), 476-480 (2005-05-03)
A facile one-pot C-benzylation of various sodium enolates derived from methyl malonate, beta-ketoesters, a beta-cyanoester, a beta-cyanosulfone, ketones and a carboxylic ester is reported. Reaction of alkoxydiphenylsulfonium salts formed by treating various benzyl alcohols with diphenyl sulfide bis(trifluoromethanesulfonate) (derived from
Enrico Baciocchi et al.
The Journal of organic chemistry, 73(15), 5675-5682 (2008-06-27)
The 3-cyano-N-methylquinolinium perchlorate (3-CN-NMQ(+)ClO4(-))-photosensitized oxidation of phenyl alkyl sulfoxides (PhSOCR1R2R3, 1, R1 = R2 = H, R3 = Ph; 2, R1 = H, R2 = Me, R3 = Ph; 3, R1 = R2 = Ph, R3 = H; 4, R1
Wen-xian Li et al.
Guang pu xue yu guang pu fen xi = Guang pu, 22(6), 905-907 (2003-08-14)
(Tb1-x Tmx).L2.(ClO4).2H2O(x = 0.000 to 0.200, L = C6H5SOCH2COO-) have been synthesized. The coordination compounds have been studied by means of composition analysis, molar conductivity, IR, and the condition of coordination have been inferred. In the fluorescent spectra it was
J A Kozlowski et al.
Bioorganic & medicinal chemistry letters, 10(20), 2255-2257 (2000-10-31)
Structure activity studies on [4-(phenylsulfonyl)phenyl]methylpiperazine led to the discovery of 4-cyclohexyl-alpha-[4-[[4-methoxyphenyl(S)-sufinyl]phenyl]-1-pi perazineacetonitrile, 1, an M2 selective muscarinic antagonist. Affinity at the cloned human M2 receptor was 2.7 nM; the M1/M2 selectivity is 40-fold.

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