P51478
丙酸酐
97%
别名:
初油酸酐
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关于此项目
线性分子式:
(CH3CH2CO)2O
化学文摘社编号:
分子量:
130.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-638-2
Beilstein/REAXYS Number:
507066
MDL number:
Assay:
97%
InChI key
WYVAMUWZEOHJOQ-UHFFFAOYSA-N
InChI
1S/C6H10O3/c1-3-5(7)9-6(8)4-2/h3-4H2,1-2H3
SMILES string
CCC(=O)OC(=O)CC
vapor density
4.5 (vs air)
vapor pressure
10 mmHg ( 57.7 °C)
assay
97%
autoignition temp.
545 °F
expl. lim.
11.9 %
Quality Level
bp
167 °C (lit.)
mp
−43 °C (lit.)
solubility
H2O: decomposes (when in contact with water)
density
1.015 g/mL at 25 °C (lit.)
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Application
丙酐可作为酰化剂用于脂肪酶催化的醇类酯化反应。近年来的研究表明，丙酸酐改性木屑制备的刨花板具有较高的尺寸稳定性。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
165.2 °F - closed cup
flash_point_c
74 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Dimensional stabilisation and strength of particleboard by chemical modification with propionic anhydride.
Papadopoulos AN & Gkaraveli A
European Journal of Wood and Wood Products, 61(2), 142-144 (2003)
Anhydrides as acylating agents in lipase-catalyzed stereoselective esterification of racemic alcohols.
Bianchi D, et al.
The Journal of Organic Chemistry, 53(23), 5531-5534 (1988)
Robert Meatherall et al.
Journal of analytical toxicology, 33(8), 525-531 (2009-10-31)
Azide in human blood and plasma samples was derivatized with propionic anhydride in a headspace vial without prior sample preparation. The reaction proceeds quickly at room temperature to form propionyl azide. A portion of the headspace was assayed by gas
Mo Xu et al.
Methods in enzymology, 512, 29-55 (2012-08-23)
In eukaryotic cells, posttranslational modifications (PTMs) on histones regulate chromatin structure and thus impact nearly all chromatin-templated events, including replication, transcription, and DNA repair. During S phase, newly synthesized histones are deposited onto DNA, leading to dilution of total chromatin-associated
Surendra Nimesh et al.
International journal of pharmaceutics, 337(1-2), 265-274 (2007-01-27)
Polyethylenimine (750 kDa) has been derivatized to influence the proton sponge mechanism and hydrophobic-hydrophilic balance. The polymer was acylated using acid anhydrides of varying carbon chain length, followed by cross-linking with PEG-bis-P to form compact nanoparticles. The chemical linkages in
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