等级
reagent grade
质量水平
蒸汽密度
4.2 (vs air)
蒸汽压
1 mmHg ( 33 °C)
方案
98%
杂质
≤1% phenol
折射率
n20/D 1.573 (lit.)
沸点
197 °C (lit.)
mp
1-2 °C (lit.)
密度
1.146 g/mL at 25 °C (lit.)
SMILES字符串
Oc1ccccc1C=O
InChI
1S/C7H6O2/c8-5-6-3-1-2-4-7(6)9/h1-5,9H
InChI key
SMQUZDBALVYZAC-UHFFFAOYSA-N
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应用
水杨醛可用作合成新型不对称手性Salen Schiff碱配体的起始试剂。它可用于制备水杨醛苯肼,其是一种滴定有机金属试剂的有用指示剂。
水杨醛(2-羟基苯甲醛)可以通过Dakin反应用于制备邻苯二酚。
警示用语:
Warning
危险分类
Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2
储存分类代码
11 - Combustible Solids
WGK
WGK 2
闪点(°F)
170.6 °F - closed cup
闪点(°C)
77 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Eagleson M.
Concise Encyclopedia Chemistry, 301-301 (1994)
The Use of Salicylaldehyde Phenylhydrazone as an Indicator for the Titration of Organometallic Reagents.
Brian E. Love et al.
The Journal of organic chemistry, 64(10), 3755-3756 (2001-10-25)
Salicin from host plant as precursor of salicylaldehyde in defensive secretion of chrysomeline larvae.
Pasteels JM, et al.
Physiological Entomology, 8(3), 307-314 (1983)
Unsymmetric chiral salen Schiff bases: A new chiral ligand pool from bis-schiff bases containing two different salicylaldehyde units.
Lopez J, et al.
Tetrahedron Letters, 39(24), 4199-4202 (1998)
Ziyad A Taha et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 81(1), 317-323 (2011-07-15)
Eight new lanthanide metal complexes [LnL(NO(3))(2)]NO(3) {Ln(III) = Nd, Dy, Sm, Pr, Gd, Tb, La and Er, L = bis-(salicyladehyde)-1,3-propylenediimine Schiff base ligand} were prepared. These complexes were characterized by elemental analysis, thermogravimetric analysis (TGA), molar conductivity measurements and spectral
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