T25305
四苯基氯化砷(V) 水合物
97%
别名:
四苯氯化砷, 苯基氯化砷
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关于此项目
线性分子式:
(C6H5)4As(Cl) · xH2O
化学文摘社编号:
分子量:
418.79 (anhydrous basis)
Beilstein:
3580063
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
97%
反应适用性
core: arsenic
reagent type: catalyst
mp
258-260 °C (lit.)
SMILES字符串
O.[Cl-].c1ccc(cc1)[As+](c2ccccc2)(c3ccccc3)c4ccccc4
InChI
1S/C24H20As.ClH.H2O/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;;/h1-20H;1H;1H2/q+1;;/p-1
InChI key
NGDWSDTZKCSLRK-UHFFFAOYSA-M
应用
阳离子交换剂。用于制备砷酰胺、肟和碳水化合物衍生物。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
P Gros et al.
Biochemistry, 31(7), 1992-1998 (1992-02-25)
The possibility that simple lipophilic cations such as tetraphenylphosphonium (TPA+), triphenylmethylphosphonium (TPMP+), and diphenyldimethylphosphonium (DDP+) are substrates for the multidrug-resistance transport protein, P-glycoprotein, was tested. Hamster cells transfected with and overexpressing mouse mdr1 or mouse mdr3 exhibit high levels of
S Manon et al.
Biochemistry and molecular biology international, 29(2), 375-385 (1993-02-01)
The effect of a group of non-usual inhibitors of ATP synthesis was investigated in yeast mitochondria. Tetraphenylphosphonium, tetraphenylarsonium and ethidium decreased the rate of ATP synthesis but did not decrease the ATP/O ratio. They did not inhibit the ATPase activity
E Bibi et al.
Proceedings of the National Academy of Sciences of the United States of America, 90(19), 9209-9213 (1993-10-01)
We describe functional expression of the mouse multidrug-resistance protein (P-glycoprotein; P-gp) in an Escherichia coli mutant defective in the outer membrane protease ompT. Heterologously expressed mdr1 appears as an unglycosylated species with an apparent molecular mass of 140 kDa in
Effect of phosphonium and arsonium salts on the differential-pulse polarograms of three permitted synthetic food colouring matters.
A G Fogg et al.
The Analyst, 112(9), 1319-1321 (1987-09-01)
A M George et al.
Archives of biochemistry and biophysics, 333(1), 66-74 (1996-09-01)
In this preliminary study, we report the cloning of the human MDR1 cDNA into a prokaryotic expression vector and the consequent functional expression of heterologous P-glycoprotein in Escherichia coli. We demonstrate increased resistance to the P-glycoprotein substrates TPA+, TPP+, and
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