Merck
CN

T45004

Sigma-Aldrich

三烯丙基胺

99%

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别名:
TAA
线性分子式:
(H2C=CHCH2)3N
CAS号:
分子量:
137.22
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

4.73 (vs air)

质量水平

蒸汽压

90 mmHg ( 80 °C)

检测方案

99%

折射率

n20/D 1.451 (lit.)

bp

150-151 °C (lit.)

密度

0.79 g/mL at 25 °C (lit.)

SMILES string

C=CCN(CC=C)CC=C

InChI

1S/C9H15N/c1-4-7-10(8-5-2)9-6-3/h4-6H,1-3,7-9H2

InChI key

VPYJNCGUESNPMV-UHFFFAOYSA-N

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此商品
T30805163678172502
Triallylamine 99%

Sigma-Aldrich

T45004

三烯丙基胺

Thioacetic acid 96%

Sigma-Aldrich

T30805

硫代醋酸

Thioacetamide ACS reagent, ≥99.0%

Sigma-Aldrich

163678

硫代乙酰胺

Thioacetamide reagent grade, 98%

Sigma-Aldrich

172502

硫代乙酰胺

refractive index

n20/D 1.451 (lit.)

refractive index

n20/D 1.465 (lit.)

refractive index

-

refractive index

-

bp

150-151 °C (lit.)

bp

88-91.5 °C (lit.)

bp

-

bp

-

density

0.79 g/mL at 25 °C (lit.)

density

1.065 g/mL at 25 °C (lit.)

density

-

density

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

vapor density

4.73 (vs air)

vapor density

-

vapor density

-

vapor density

-

应用

  • 在钌催化剂的存在下,三烯丙基胺(TAA)可与伯芳族胺反应形成2-乙基-3-甲基喹啉。
  • TAA通过加氢锆化反应,然后用四氯化锗进行金属转移,形成1-氮杂-5-锗-5-氯双环[3.3.3]十一烷。该化合物可与格氏试剂或锂试剂反应形成相应的5-有机化合物。
  • TAA可与氟化1,3,4-恶二唑发生环加成反应,从而生成八氢-2,7-甲呋喃[3,2-c]吡啶。

警示用语:

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

87.8 °F - closed cup

闪点(°C)

31 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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