T79758
三甲基膦酰基乙酸酯
98%
别名:
NSC 84262, （羧甲基）膦酸三甲酯
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线性分子式:
(CH3O)2P(O)CH2CO2CH3
化学文摘社编号:
分子量:
182.11
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
EC Number:
227-663-0
Beilstein/REAXYS Number:
1865177
MDL number:
产品名称
三甲基膦酰基乙酸酯, 98%
InChI
1S/C5H11O5P/c1-8-5(6)4-11(7,9-2)10-3/h4H2,1-3H3
InChI key
SIGOIUCRXKUEIG-UHFFFAOYSA-N
SMILES string
COC(=O)CP(=O)(OC)OC
assay
98%
reaction suitability
reaction type: C-C Bond Formation
refractive index
n20/D 1.437 (lit.)
bp
118 °C/0.85 mmHg (lit.)
265-268 °C (lit.)
density
1.125 g/mL at 25 °C (lit.)
Quality Level
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Application
作为以下反应的反应物：
- 分子内Mannich型反应可产生sarain A重氮三环核
- 有机催化的oxa-Michael反应
- 羟吲哚的异戊烯化和香叶基化
- 分子内Horner-Wadsworth-Emmons反应
- 烯烃交叉复分解/杂环化
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
B R DeMark et al.
Archives of biochemistry and biophysics, 223(2), 360-368 (1983-06-01)
The effects of the inhibitors trimethylacetyl phosphate and cAMP have been determined in reactions catalyzed by D-glyceraldehyde-3-phosphate dehydrogenase. These inhibitors must influence the oxidation of aldehydes through substrate dependent cooperative conformational changes. Both trimethylacetyl phosphate and cAMP give sigmoidal 1/V
Alastair B Ross et al.
The Journal of nutrition, 143(6), 766-773 (2013-04-26)
Epidemiological studies consistently find that diets rich in whole-grain (WG) cereals lead to decreased risk of disease compared with refined grain (RG)-based diets. Aside from a greater amount of fiber and micronutrients, possible mechanisms for why WGs may be beneficial
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