T80489
三甲基碘化锍
98%
别名:
三甲基氢碘化λ[3]-硫烷, 三甲基碘代磺酸
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关于此项目
线性分子式:
(CH3)3S(I)
化学文摘社编号:
分子量:
204.07
Beilstein:
3555192
EC 号:
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22
方案
98%
反应适用性
reaction type: C-C Bond Formation
mp
215-220 °C (lit.)
SMILES字符串
[I-].C[S+](C)C
InChI
1S/C3H9S.HI/c1-4(2)3;/h1-3H3;1H/q+1;/p-1
InChI key
VFJYIHQDILEQNR-UHFFFAOYSA-M
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一般描述
三甲基磺酸碘通常用作有机合成中的甲基化剂。
应用
用强碱处理可生成二甲基亚甲基锍，而后又可参与酮的羰基原位反应形成环氧化物或烯丙醇。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Facile access to S-methyl dithiocarbamates with sulfonium or sulfoxonium iodide as a methylation reagent
Deng H, et al.
Organic & Biomolecular Chemistry, 21(32), 6474-6478 (2023)
Tetrahedron Letters, 35, 2009-2009 (1994)
K D Müller et al.
Zentralblatt fur Bakteriologie : international journal of medical microbiology, 274(2), 174-182 (1990-11-01)
Gas-liquid chromatography of cellular fatty acids is a useful tool for the identification of bacteria. Derivatization of bacterial fatty acids to methyl esters by conventional techniques is usually time-consuming and complicated. A new one-step technique using trimethyl-sulfonium hydroxide allows the
K Müller et al.
Journal of clinical microbiology, 36(9), 2477-2480 (1998-08-15)
The MIDI automated Microbial Identification System (MIS) uses gas chromatography (GC) analysis of whole-cell fatty acid methyl esters (FAMEs) between 9 and 20 carbons in length to characterize a wide range of bacterial genera and species, including mycobacteria. Mycolic acid
Yasuyuki Ishida et al.
Journal of chromatography. A, 1216(15), 3296-3299 (2009-02-19)
Reaction efficiencies of two organic alkalis, tetramethylammonium hydroxide (TMAH) and trimethylsulfonium hydroxide (TMSH), with lipids during thermally assisted hydrolysis and methylation (THM) were examined focusing on (1) the types of lipids and (2) degree of unsaturation of fatty acid moieties.
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