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T80489

三甲基碘化锍

Name: 三甲基碘化锍
Brand: ALDRICH

98%

别名:

三甲基氢碘化λ[3]-硫烷, 三甲基碘代磺酸

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关于此项目

线性分子式:

(CH₃)₃S(I)

化学文摘社编号:

2181-42-2

分子量:

204.07

UNSPSC Code:

12352101

NACRES:

NA.22

PubChem Substance ID:

24900497

EC Number:

218-555-4

Beilstein/REAXYS Number:

3555192

MDL number:

MFCD00011632

Assay:

98%

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属性

Quality Level

200

assay

98%

reaction suitability

reaction type: C-C Bond Formation

mp

215-220 °C (lit.)

SMILES string

[I-].C[S+](C)C

InChI

1S/C3H9S.HI/c1-4(2)3;/h1-3H3;1H/q+1;/p-1

InChI key

VFJYIHQDILEQNR-UHFFFAOYSA-M

说明

General description

三甲基磺酸碘通常用作有机合成中的甲基化剂。

Application

用强碱处理可生成二甲基亚甲基锍，而后又可参与酮的羰基原位反应形成环氧化物或烯丙醇。

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Solvent effects on methyl transfer reactions. 2. The reaction of amines with trimethylsulfonium salts.

H Castejon et al.

Journal of the American Chemical Society, 123(25), 6092-6097 (2001-06-21)

The reaction of ammonia and pyridine with trimethylsulfonium ion has been studied in gas phase and solution. Density functional theory at the B3LYP/6-31+G level was used to describe the energy changes along the reaction coordinate in the gas phase, and

A new and rapid method for the assay of bacterial fatty acids using high resolution capillary gas chromatography and trimethylsulfonium hydroxide.

K D Müller et al.

Zentralblatt fur Bakteriologie : international journal of medical microbiology, 274(2), 174-182 (1990-11-01)

Gas-liquid chromatography of cellular fatty acids is a useful tool for the identification of bacteria. Derivatization of bacterial fatty acids to methyl esters by conventional techniques is usually time-consuming and complicated. A new one-step technique using trimethyl-sulfonium hydroxide allows the

Improved identification of mycobacteria by using the microbial identification system in combination with additional trimethylsulfonium hydroxide pyrolysis.

K Müller et al.

Journal of clinical microbiology, 36(9), 2477-2480 (1998-08-15)

The MIDI automated Microbial Identification System (MIS) uses gas chromatography (GC) analysis of whole-cell fatty acid methyl esters (FAMEs) between 9 and 20 carbons in length to characterize a wide range of bacterial genera and species, including mycobacteria. Mycolic acid

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全球贸易项目编号

货号	GTIN
T80489-25G	04061837378843
T80489-100G	04061837378836