T80489
三甲基碘化锍
98%
别名:
三甲基氢碘化λ[3]-硫烷, 三甲基碘代磺酸
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关于此项目
线性分子式:
(CH3)3S(I)
化学文摘社编号:
分子量:
204.07
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
218-555-4
Beilstein/REAXYS Number:
3555192
MDL number:
Assay:
98%
产品名称
三甲基碘化锍, 98%
InChI key
VFJYIHQDILEQNR-UHFFFAOYSA-M
InChI
1S/C3H9S.HI/c1-4(2)3;/h1-3H3;1H/q+1;/p-1
SMILES string
[I-].C[S+](C)C
assay
98%
reaction suitability
reaction type: C-C Bond Formation
mp
215-220 °C (lit.)
Quality Level
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Application
用强碱处理可生成二甲基亚甲基锍，而后又可参与酮的羰基原位反应形成环氧化物或烯丙醇。
General description
三甲基磺酸碘通常用作有机合成中的甲基化剂。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
C Díez et al.
Journal of chromatography. A, 1125(2), 244-253 (2006-06-20)
In this study, an orthogonal array design was applied to know the way different parameters affected the derivatization of some herbicides that are commonly applied in the soils. Herbicides formulated as esters have been reported to rapidly hydrolyse, in contact
Tetrahedron Letters, 35, 2009-2009 (1994)
K D Müller et al.
Zentralblatt fur Bakteriologie : international journal of medical microbiology, 274(2), 174-182 (1990-11-01)
Gas-liquid chromatography of cellular fatty acids is a useful tool for the identification of bacteria. Derivatization of bacterial fatty acids to methyl esters by conventional techniques is usually time-consuming and complicated. A new one-step technique using trimethyl-sulfonium hydroxide allows the
Yasuyuki Ishida et al.
Journal of chromatography. A, 1216(15), 3296-3299 (2009-02-19)
Reaction efficiencies of two organic alkalis, tetramethylammonium hydroxide (TMAH) and trimethylsulfonium hydroxide (TMSH), with lipids during thermally assisted hydrolysis and methylation (THM) were examined focusing on (1) the types of lipids and (2) degree of unsaturation of fatty acid moieties.
Jörg Schönherr
Pest management science, 58(4), 343-351 (2002-04-27)
Penetration of glyphosate salts across isolated poplar (Populus canescens (Aiton) Sm) cuticular membranes (CM) was studied using Na+, K+, NH4+, trimethylsulfonium+ (TMS) and isopropylamine+ (IPA) as cations. After droplet drying, humidity over the salt residues on the outer surfaces of
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