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线性分子式:
(CH3)3S(I)O
化学文摘社编号:
分子量:
220.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-204-2
Beilstein/REAXYS Number:
3595854
MDL number:
Assay:
98%
产品名称
三甲基碘化亚砜, 98%
InChI
1S/C3H9OS.HI/c1-5(2,3)4;/h1-3H3;1H/q+1;/p-1
InChI key
BPLKQGGAXWRFOE-UHFFFAOYSA-M
SMILES string
[I-].C[S+](C)(C)=O
assay
98%
mp
208-212 °C (dec.) (lit.)
Quality Level
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Application
用强碱处理可生成内鎓盐,内鎓盐可与酮和醛的羰基发生加成反应生成环氧化物。也可优先与 α,β-不饱和酯的双键发生加成反应生成环丙酯。
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Tetrahedron, 48, 5089-5089 (1992)
Tetrahedron, 49, 5067-5067 (1993)
Optical phonons, crystal-field transitions, and europium luminescence-excitation processes in Eu2BaCoO5: Experiment and theory.
Taboada et al.
Physical review. B, Condensed matter, 50(13), 9157-9168 (1994-10-01)
The Journal of Organic Chemistry, 58, 3148-3148 (1993)
W T Ashton et al.
Journal of medicinal chemistry, 35(11), 2103-2112 (1992-05-29)
A series of transition-state analogues having heterocyclythio C-termini has been synthesized and evaluated for inhibition of human renin. Addition of mercaptoheterocycles to a chiral Boc-amino epoxide intermediate led, after several steps, to the target [(2R,3S)-3-(BocPheHis-amino)-4-cyclohexyl-2-hydroxy-1-butyl]thio derivatives. Oxidation of the thioether
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