W419501
苯酞
98%
别名:
2-苯并呋喃酮
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关于此项目
经验公式（希尔记法）:
C8H6O2
化学文摘社编号:
分子量:
134.13
Flavis number:
10.056
PubChem Substance ID:
UNSPSC Code:
12164502
FEMA Number:
4195
EC Number:
201-744-0
MDL number:
Beilstein/REAXYS Number:
114632
产品名称
苯酞, 98%
InChI
1S/C8H6O2/c9-8-7-4-2-1-3-6(7)5-10-8/h1-4H,5H2
InChI key
WNZQDUSMALZDQF-UHFFFAOYSA-N
SMILES string
O=C1OCc2ccccc12
biological source
synthetic
assay
98%
bp
290 °C (lit.)
mp
71-74 °C (lit.)
application(s)
flavors and fragrances
organoleptic
coconut
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存储类别
13 - Non Combustible Solids
wgk
WGK 1
flash_point_f
305.6 °F - closed cup
flash_point_c
152 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Tsz-Ying Yuen et al.
Organic letters, 14(19), 5154-5157 (2012-09-29)
A highly convergent total synthesis of 7',8'-dihydroaigialospirol is described. Key steps of the synthesis include a Nozaki-Hiyama-Kishi (NHK) coupling of an iodoalkyne with an advanced phthalide-aldehyde and a remarkable one-pot acid-mediated global deprotection/spiroacetalization.
Juan Mangas-Sánchez et al.
Organic letters, 14(6), 1444-1447 (2012-03-08)
A straightforward synthesis of (S)-3-methylphthalides has been developed, with the key asymmetric step being the bioreduction of 2-acetylbenzonitriles. Enzymatic processes have been found to be highly dependent on the pH value, with acidic conditions being required to avoid undesired side
Zhishi Ye et al.
The Journal of organic chemistry, 75(17), 6043-6045 (2010-08-28)
A palladium-catalyzed addition of arylboronic acids to phthalaldehyde, followed by an intramolecular lactonization to access 3-substituted phthalides, is described. The procedure tolerates a series of functional groups, such as methoxyl, fluoro, chloro, and trifluoromethyl groups. It represents a procedure for
R Santhosh Reddy et al.
Organic & biomolecular chemistry, 10(18), 3655-3661 (2012-04-13)
The asymmetric dihydroxylation (AD) of o-cyano cinnamates and styrene derivatives leads to efficient construction of chiral phthalide frameworks in high optical purities. This unique reaction is characterized by unusual synergism between CN and osmate groups resulting in rate enhancement of
Vatcharin Rukachaisirikul et al.
Journal of natural products, 75(5), 853-858 (2012-04-25)
Nine new fungal metabolites, one phthalide derivative, acremonide (1), and eight isocoumarin derivatives, acremonones A-H (2-9), were isolated from the mangrove-derived fungus Acremonium sp. PSU-MA70 together with 10 known compounds. Their structures were determined by NMR analysis. The known 8-deoxytrichothecin
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