W519103
甲酸甲酯
≥95%
别名:
蚁酸甲酯
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线性分子式:
HCO2CH3
化学文摘社编号:
分子量:
60.05
NACRES:
NA.21
Flavis number:
9.642
PubChem Substance ID:
UNSPSC Code:
12164502
EC Number:
203-481-7
MDL number:
Beilstein/REAXYS Number:
1734623
Assay:
≥95%
Bp:
32-34 °C (lit.)
InChI key
TZIHFWKZFHZASV-UHFFFAOYSA-N
InChI
1S/C2H4O2/c1-4-2-3/h2H,1H3
SMILES string
[H]C(=O)OC
biological source
synthetic
vapor density
2.1 (vs air)
assay
≥95%
form
liquid
autoignition temp.
842 °F
expl. lim.
23 %
refractive index
n20/D 1.343 (lit.)
pH
4.0-5.0 (20 °C, 200 g/L)
bp
32-34 °C (lit.)
mp
−100 °C (lit.)
density
0.974 g/mL at 20 °C (lit.)
application(s)
flavors and fragrances
documentation
see Safety & Documentation for available documents
food allergen
no known allergens
organoleptic
fruity; plum
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General description
Methyl formate finds application as a fumigant in raisins and dried currants.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
-2.2 °F - closed cup
flash_point_c
-19 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
新产品
此项目有
Winter R
A Consumer's Dictionary of Food Additives, 352-352 null
Alexandre Faure et al.
The Journal of chemical physics, 135(2), 024301-024301 (2011-07-20)
A potential energy surface for helium interacting with methyl formate has been computed using high-level electronic structure methods. The interaction energies obtained on a three-dimensional grid have been fitted by an analytic function of interatomic distances with correct asymptotic behavior
A Nihlén et al.
International archives of occupational and environmental health, 73(7), 479-487 (2000-11-01)
A toxicokinetic (TK) model was developed to describe the inhalation exposure in humans to methyl formate (MF), a catalyst used in foundries, and to discuss biological monitoring. The TK model consisted of four compartments: MF, the metabolites--methanol (MeOH) and formic
Hiroya Yurimoto et al.
Yeast (Chichester, England), 21(4), 341-350 (2004-03-26)
Methyl formate synthesis during growth on methanol by methylotrophic yeasts has been considered to play a role in formaldehyde detoxification. An enzyme that catalyses methyl formate synthesis was purified from methylotrophic yeasts, and was suggested to belong to a family
Kristin Skinner et al.
Applied and environmental microbiology, 75(17), 5514-5522 (2009-07-08)
The filamentous fungus Graphium sp. (ATCC 58400) grows on gaseous n-alkanes and diethyl ether. n-Alkane-grown mycelia of this strain also cometabolically oxidize the gasoline oxygenate methyl tert-butyl ether (MTBE). In this study, we characterized the ability of this fungus to
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