X1202
间苯二甲胺
99%
别名:
1,3-苯二甲胺, m-XDA, 1,3-二(氨甲基)苯, α,α′-二氨基间二甲苯
蒸汽压
15 mmHg ( 145 °C)
方案
99%
折射率
n20/D 1.571 (lit.)
沸点
265 °C/745 mmHg (lit.)
密度
1.032 g/mL at 25 °C (lit.)
SMILES字符串
NCc1cccc(CN)c1
InChI
1S/C8H12N2/c9-5-7-2-1-3-8(4-7)6-10/h1-4H,5-6,9-10H2
InChI key
FDLQZKYLHJJBHD-UHFFFAOYSA-N
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应用
间苯二甲胺可用于：
- 作为聚(乙烯基-氨基甲酸乙酯)类玻璃高分子(vitrimer)的合成单体。
- 作为氨基甲酸酯保护多取代双胍合成的起始材料。
- 通过二醇的催化脱氢反应合成聚酰胺。
警示用语：
Danger
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1B
补充剂危害
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 2
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Vinylogous urethane vitrimers.
Denissen W, et al.
Advances in Functional Materials, 25(16), 2451-2457 (2015)
Direct synthesis of polyamides via catalytic dehydrogenation of diols and diamines.
Zeng H and Guan Z
Journal of the American Chemical Society, 133(5), 1159-1161 (2011)
A versatile one-pot synthesis of 1, 3-substituted guanidines from carbamoyl isothiocyanates.
Linton BR, et al.
The Journal of Organic Chemistry, 65(5), 1566-1568 (2000)
J Simal Gándara et al.
Food additives and contaminants, 10(5), 555-565 (1993-09-01)
The overall and specific migrations of BADGE n = 0 monomer and m-XDA hardener from a BEPOX LAB 889 (Gairesa internal code), epoxy system cured at room temperature, into three water-based food simulants are studied. Hydrolysis of BADGE n =
G Richter et al.
Dermatosen in Beruf und Umwelt. Occupation and environment, 38(4), 117-120 (1990-07-01)
We found m-xylylene diamine, a widespread additive in plastics, to be a very potent sensitizer. Patch tests with other diamines revealed in all four patients allergic cross reactions to benzylamine. Two persons had also acquired an additional allergy to ethylenediamine.
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