X1202
间苯二甲胺
99%
别名:
1,3-苯二甲胺, m-XDA, 1,3-二(氨甲基)苯, α,α′-二氨基间二甲苯
蒸汽压
15 mmHg ( 145 °C)
质量水平
方案
99%
折射率
n20/D 1.571 (lit.)
沸点
265 °C/745 mmHg (lit.)
密度
1.032 g/mL at 25 °C (lit.)
SMILES字符串
NCc1cccc(CN)c1
InChI
1S/C8H12N2/c9-5-7-2-1-3-8(4-7)6-10/h1-4H,5-6,9-10H2
InChI key
FDLQZKYLHJJBHD-UHFFFAOYSA-N
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应用
间苯二甲胺可用于：
- 作为聚(乙烯基-氨基甲酸乙酯)类玻璃高分子(vitrimer)的合成单体。
- 作为氨基甲酸酯保护多取代双胍合成的起始材料。
- 通过二醇的催化脱氢反应合成聚酰胺。
警示用语：
Danger
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1B
补充剂危害
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 2
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Saverio Cellamare et al.
Bioorganic & medicinal chemistry, 16(9), 4810-4822 (2008-04-15)
A series of N-terminus benzamides of glycine-based symmetric peptides, linked to m-xylylenediamine and 3,4'-oxydianiline spacers, were prepared and tested as inhibitors of beta-amyloid peptide Abeta(1-40) aggregation in vitro. Compounds with good anti-aggregating activity were detected. Polyphenolic amides showed the highest
Yongmei Zhao et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(25), 6621-6629 (2006-06-07)
Polynuclear copper complexes with two or three Cu(BPA) (BPA, bis(2-pyridylmethyl)amine) motifs, [Cu2(mTPXA)Cl4]3 H2O (1), [Cu2(pTPXA)Cl4]3 H2O (2), [Cu3(HPTAB)Cl5]Cl3 H2O (3) (mTPXA = N,N,N',N'-tetra-(2-pyridylmethyl)-m-xylylene diamine; pTPXA = N,N, N',N'-tetra-(2-pyridylmethyl)-p-xylylenediamine; HPTAB = N,N,N',N',N'',N''-hexakis(2-pyridylmethyl)-1,3,5-tris-(aminomethyl)benzene) have been synthesized and characterized. The crystal structures of
Vinylogous urethane vitrimers.
Denissen W, et al.
Advances in Functional Materials, 25(16), 2451-2457 (2015)
K D Rice et al.
Bioorganic & medicinal chemistry letters, 10(20), 2357-2360 (2000-10-31)
The synthesis and optimization of a novel class of reversible and active-site directed dibasic inhibitors of human mast cell tryptase are described. The compounds were shown to be both remarkably potent and selective for tryptase with Ki values for optimized
Occupational contact dermatitis due to the epoxy hardener m-xylylenediamine.
S Sommer et al.
Contact dermatitis, 44(6), 374-374 (2001-06-22)
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