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About This Item

UNSPSC代码:
12352305
NACRES:
NA.21
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Product Name

氢氧化钾溶液(乙醇基质), c(KOH) = 0.5 mol/l (0.5 N), Titripur®, reag. Ph. Eur.

Agency

reag. Ph. Eur.

质量水平

蒸汽压

59 hPa ( 20 °C)

产品线

Titripur®

表单

liquid

自燃温度

425 °C (ethanol)

质量

Analyzed in our ISO 17025 accredited QC lab

expl. lim.

3.5-15.0 % (v/v) ethanol()

反应适用性

reaction type: Acid-base reactions

浓度

0.5 M

技术

titration: suitable

pH值(酸碱度)

14 (20 °C in H2O)

沸点

78.3 °C/1013 hPa (ethanol)

mp

-114.5 °C (ethanol)

转变温度

flash point 12 °C (ethanol)

密度

0.85 g/cm3 at 20 °C

储存温度

15-25°C

应用


  • Voltammetric Determination: Potassium hydroxide solution in ethanol is used in voltammetric determination of antioxidants in various matrices. A recent study demonstrated its application in the voltammetric determination of the antioxidant 2,6-di-tert-butyl-p-cresol (T501) in transformer oil using a graphite electrode. This method enhances the sensitivity and accuracy of antioxidant detection, crucial for ensuring the stability and performance of oils and other industrial fluids (Zhou et al., Analytical Letters, 2021).

特点和优势

Accreditation:
This volumetric solution is analyzed by our calibration laboratory D-K-15185-01-00 which is accredited according to DIN EN ISO/IEC 17025 for analysis of amount-of-substance concentrations in volumetric solutions by DAkkS (Deutsche Akkreditierungsstelle - German National Accreditation Body). The accreditation certificate can be found at www.sigmaaldrich.com/ISO17025.

包装

SKU-pack size numbers ending with a "3" are SmartChemicals with an RFID tag on the label for seamless data transfer to the instrument, e.g. xxxxxx1003 or xxxxxxx 4003. More information on www.sigmaaldrich.com/SmartChemicals

分析说明

Form liquid
Amount-of-substance concentration 0.4975 - 0.5025 mol/L
Measurement uncertainty ± 0.0015 mol/L
Traceability NIST SRM

The concentration is determined by volumetric titration and refers to 20°C.
The amount-of-substance concentration of this volumetric solution is traceable to a primary standard reference material (SRM) from the National Institute of Standards and Technology, Gaithersburg, USA (NIST SRM 350 benzoic acid) by means of volumetric standard benzoic acid (article number 1.02401), certified reference material according to ISO 17034, analyzed by our accredited calibration laboratory of Merck KGaA, Darmstadt, Germany according to DIN EN ISO/IEC 17025. The uncertainty is expressed as expanded measurement uncertainty with a coverage factor k=2 covering a confidence level of 95%.

Note: The titer is a correction factor to correct for variations of the volumetric solution, the titration equipment, the temperature and other laboratory conditions. For correct titration results it is recommended to determine a titer with the laboratory specific equipment and under laboratory specific conditions directly after opening a new bottle and at regular time intervals.

法律信息

Titripur is a registered trademark of Merck KGaA, Darmstadt, Germany

象形图

FlameCorrosion

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1B

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

53.6 °F - (ethanol)

闪点(°C)

12 °C - (ethanol)


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