8.05894
4-甲基吗啉
for synthesis
别名:
4-甲基吗啉
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关于此项目
经验公式（希尔记法）:
C5H11NO
化学文摘社编号:
分子量:
101.15
UNSPSC Code:
12352005
EC Index Number:
203-640-0
NACRES:
NA.22
MDL number:
Assay:
≥98% (GC)
Grade:
synthesis grade
Bp:
112-114 °C/1013 hPa
Vapor pressure:
23.5 hPa ( 20 °C)
grade
synthesis grade
Quality Level
vapor pressure
23.5 hPa ( 20 °C)
assay
≥98% (GC)
form
liquid
autoignition temp.
165 °C (DIN 51794)
potency
1960 mg/kg LD50, oral (Rat), 1240 mg/kg LD50, skin (Rabbit)
expl. lim.
2.1 % (v/v)
dilution
(for synthesis)
pH
10.6 (20 °C, 50 g/L in H2O)
bp
112-114 °C/1013 hPa
mp
-66 °C
transition temp
flash point 12.5 °C (DIN 51755 Part 1)
density
0.92 g/cm3 at 20 °C
storage temp.
2-30°C
SMILES string
N1(CCOCC1)C
InChI
1S/C5H11NO/c1-6-2-4-7-5-3-6/h2-5H2,1H3
InChI key
SJRJJKPEHAURKC-UHFFFAOYSA-N
Application
4-甲基吗啡啉可用作：
- 前体，用于制备N-甲基吗啡啉N-氧化物和1-丁基-1-甲基溴化啉([BMmo][Br])，一种单离子液体。
- 反应物，用于合成季铵络合物，可作为氧化还原液流电池中的络合剂。
- 碱性催化剂，用于通过Willgerodt-Kindler反应合成硫苯酰胺。
- 活化剂，用于合成化妆品、制药和营养保健品中的透明质酸基生物聚合物。
Analysis Note
含量（GC，area%）： ≥ 98 %
密度（d 20 °C/ 4 °C）：0.917 - 0.918
同一性（IR）：通过测试
密度（d 20 °C/ 4 °C）：0.917 - 0.918
同一性（IR）：通过测试
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
53.6 °F - closed cup - DIN 51755 Part 1
flash_point_c
12 °C - closed cup - DIN 51755 Part 1
法规信息
危险化学品
此项目有
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Jiale Yang et al.
Journal of agricultural and food chemistry, 66(36), 9418-9425 (2018-08-23)
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Enantioselective arene epoxidation under mild conditions by Jacobsen catalyst: The role of protic solvent and co-catalyst in the activation of hydrogen peroxide
Rocha M, et al.
Applied Catalysis A: General, 460, 116-123 (2013)
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