8.18204
N-(Trimethylsilyl)imidazole
for synthesis
别名:
N-(Trimethylsilyl)imidazole, TSIM
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关于此项目
经验公式（希尔记法）:
C6H12N2Si
化学文摘社编号:
分子量:
140.26
UNSPSC Code:
12352103
EC Index Number:
242-040-3
NACRES:
NA.22
MDL number:
Form:
liquid
Quality Level
form
liquid
autoignition temp.
540 °C (DIN 51794)
kinematic viscosity
2.5 cSt(25 °C)
bp
212 °C (decomposition)
mp
-42 °C
transition temp
flash point 66 °C (DIN 51755 Part 1)
density
0.955-0.959 g/cm3 at 25 °C
storage temp.
2-30°C
SMILES string
[Si]([n]1cncc1)(C)(C)C
InChI
1S/C6H12N2Si/c1-9(2,3)8-5-4-7-6-8/h4-6H,1-3H3
InChI key
YKFRUJSEPGHZFJ-UHFFFAOYSA-N
Application
- Sterol Analysis: Describes the use of N-trimethylsilylimidazole for derivatizing sterols to facilitate fast GLC/MS analysis, which can be completed in under 12.5 minutes. This application is significant for analytical chemistry, particularly in sterol analysis (M Giera, F Plossl, F Bracher, 2023).
- Synthesis of Aryl-5-arylideneimidazol-4-ones: Discusses a new method using N-Trimethylsilylimidazole for the synthesis of 2,3-diaryl-5-arylidene-4imidazolones, involving a dehydration reaction of N-substituted α,β-unsaturated carbonyl compounds, which is pertinent to medicinal chemistry (VO Topuzyan, SR Tosunyan, ER Aleksanyan, 2023).
- Preparation of Ionic Liquids: Outlines the synthesis of 1, 3-bis-(3-sulfonic acid) propyl imidazolium ionic liquids using N-trimethylsilylimidazole, illustrating its utility in the development of new ionic liquid frameworks useful in materials science (K Yuan, W Huang, T Zhang, L Lv, Y Wang, Z Zou, 2023).
- Ultrasonic synthesis of stable oil filled microcapsules: This study explores the ultrasonic synthesis of oil-filled microcapsules using thiolated chitosan, potentially involving derivatives like ᴅʟ-N-Acetylhomocysteine thiolactone for improved stability and functional properties. The research provides insights into advanced microencapsulation techniques relevant in pharmaceutical and industrial applications (Source).
Analysis Note
Assay (HClO₄): ≥ 97.0 %
Density (d 20 °C/ 4 °C): 0.952 - 0.958
Identity (IR): passes test
Density (d 20 °C/ 4 °C): 0.952 - 0.958
Identity (IR): passes test
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2
signalword
Danger
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
42.8 °F - closed cup
flash_point_c
6 °C - closed cup
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 8182040025 | 04022536430126 |
| 8182040100 | 04027269244354 |