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Merck
CN

MX1456

Supelco

二甲基亚砜

OmniSolv®

别名:

DMSO, 甲基亚砜

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关于此项目

线性分子式:
(CH3)2SO
CAS Number:
分子量:
78.13
Beilstein:
506008
MDL编号:
UNSPSC代码:
12352119
EC索引号:
200-664-3
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蒸汽密度

2.7 (vs air)

质量水平

蒸汽压

0.42 mmHg ( 20 °C)

产品线

OmniSolv®

方案

≥99.9% (GC)

表单

liquid

自燃温度

573 °F

expl. lim.

42 %, 63 °F

技术

HPLC: suitable
LC/MS: suitable
gas chromatography (GC): suitable

杂质

≤0.05% Water (H2O)

蒸发残留物

≤5 ppm

颜色

APHA: ≤10

折射率

n20/D 1.479 (lit.)

沸点

189 °C (lit.)

mp

16-19 °C (lit.)

转变温度

flash point 87 °C

溶解性

1000 g/L

密度

1.10 g/mL (lit.)

UV cutoff

≤263 nm

紫外吸收

λ: 263 nm Amax: ≤1.00
λ: 270 nm Amax: ≤0.40
λ: 275 nm Amax: ≤0.25
λ: 280 nm Amax: ≤0.20
λ: 335 nm Amax: ≤0.02
λ: 350-400 nm Amax: ≤0.01

运输

ambient

储存温度

room temp

SMILES字符串

CS(C)=O

InChI

1S/C2H6OS/c1-4(2)3/h1-2H3

InChI key

IAZDPXIOMUYVGZ-UHFFFAOYSA-N

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一般描述

Dimethyl sulfoxide (DMSO) is an organosulfur compound which is a dipolar aprotic solvent. It remains liquid across a broad temperature range, acts as a strong electron donor, and possesses high polarity. These characteristics make it an excellent and selective solvent for a variety of organic and even polymeric compounds. DMSO is a widely used solvent in organic synthesis and analytical applications since it is fully miscible with water and various organic solvents, enabling it to dissolve both polar and nonpolar substances.

应用

DMSO is used
  • As a solvent in the synthesis of 3,5-Diiodo-8-aryl-BODIPYs by Double Aromatic Finkelstein Reaction.
  • As a green solvent in the preparation of novel anticorrosive epoxy coatings.
  • As solvent in H1 nuclear magnetic spectroscopy technique.
MX1456P-6 and MX1456P-1 are packaged in poly coated glass bottles
OmniSolv®

包装

M-Bottle for Solvents
As a global leader in lab reagents, we are constantly looking for new ways to optimize the safety of our products. The newly developed 4L solvent bottle design features advanced sealing technology that eliminates leaks to make the handling of solvents safer and more convenient than ever before.
See all the new features here!
is packaged in 1L Polycoated glass bottle
is packaged in 4L amber glass bottle
is packaged in 4L polycoated glass bottle

制备说明

Product filtered through a 0.2 μm filter

分析说明

Assay (GC)99.9% minColor (APHA)10 maxEvaporation residue5ppm maxFiltered through 0.2 µm filterTo pass testFormClear liquidInfrared SpectrumConforms to standardUV Abs. at 263 nm1.00AU maxUV Abs. at 270 nm0.40AU maxUV Abs. at 275 nm0.25AU maxUV Abs. at 280 nm0.20AU maxUV Abs. at 335 nm0.02AU maxUV Abs. at 350 - 400 nm0.01AU maxUV Cut-off263nm maxWater (H2O)0.05% max

法律信息

OMNISOLV is a registered trademark of Merck KGaA, Darmstadt, Germany

免责声明

在室温下容易过冷并缓慢重融。 固化产品可以通过加热至室温来重新液化,而不会损害产品。

储存分类代码

10 - Combustible liquids

WGK

WGK 1

闪点(°F)

188.6 °F - closed cup

闪点(°C)

87 °C - closed cup

法规信息

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title={The applications of dimethyl sulfoxide as reagent in organic synthesis}, author={}, journal={}, volume={358}, number={3}, pages={}, year={2016}
Wu, Xiao-Feng and Natte, Kishore
advanced synthesis and catalysis, 358, 336-352 (2016)
title={Synthesis and reactivity of 3, 5-diiodo-BODIPYs via a concerted, double aromatic finkelstein reaction}, author={, Paul G and Hall, Michael J and Knight, Julian G}, journal={}, volume={23}, number={21}, pages={}, year={2021}
Frank, Felicity J and Waddell et.al
Organic Letters, 23, 8595-8599 (2021)
Oxidation of dimethyl sulfoxide solutions by electrochemical reduction of oxygen
Sharon, Daniel and Afri, et.al.
The Journal of Physical Chemistry Letters, 4, 3115-3119 (2013)
Multinuclear NMR spectroscopy for differentiation of molecular configurations and solvent properties between acetone and dimethyl sulfoxide
Wen, Yuan-Chun and Kuo,
Journal of Molecular Structure, 1109, 154-160 (2016)
Dimethyl sulfoxide: yesterday's solvent, today's reagent
Tashrifi, Zahra and Khanaposhtani et.al.
Advanced Synthesis & Catalysis, 362, 65-86 (2020)

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