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Merck
CN

07-3750

二碘甲烷

SAJ first grade, ≥98.0%

别名:

碘化亚甲基

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经验公式(希尔记法):
CH2I2
化学文摘社编号:
分子量:
267.84
EC Number:
200-841-5
UNSPSC Code:
12352101
PubChem Substance ID:
Beilstein/REAXYS Number:
1696892
MDL number:
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InChI key

NZZFYRREKKOMAT-UHFFFAOYSA-N

InChI

1S/CH2I2/c2-1-3/h1H2

SMILES string

ICI

grade

SAJ first grade

vapor density

9.25 (vs air)

assay

≥98.0%

form

liquid

availability

available only in Japan

bp

67-69 °C/11 mmHg (lit.)

mp

5-8 °C (lit.)

density

3.325 g/mL at 25 °C (lit.)

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pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

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Qingyu Kong et al.
The journal of physical chemistry. A, 109(45), 10451-10458 (2006-07-13)
Various molecular species are known to form during the photoreaction of C2H4I2 in the gas phase and in solution. We have studied all species involved in this reaction by ab initio and density functional theory (DFT) calculations: Geometries, energies, and
Eun Chul Cho et al.
Langmuir : the ACS journal of surfaces and colloids, 24(18), 9974-9978 (2008-08-21)
This study presents a method to measure the contact angles of oils on a substrate in water. Diiodomethane and perfluorodecalin were used as model oils. Self-assembled monolayers (SAMs) were prepared by adjusting the mole ratio of CH 3- and OH-terminated
H Ihee et al.
Science (New York, N.Y.), 309(5738), 1223-1227 (2005-07-16)
We report direct structural evidence of the bridged radical (CH2ICH2.) in a polar solution, obtained using time-resolved liquid-phase x-ray diffraction. This transient intermediate has long been hypothesized to explain stereo-chemical control in many association and/or dissociation reactions involving haloalkanes. Ultrashort
Kevin Cheng et al.
Organic letters, 13(9), 2346-2349 (2011-04-06)
A diastereoselective synthesis of trans-2-substituted cyclopropanols is outlined. Bimetallic CH(2)(ZnI)(2) was found to react with α-chloroaldehydes to give cyclopropanols in yields of 64-89% and dr's ≥ 10:1. The high trans-selectivity resulted from equilibration of the cyclopropoxide intermediates.
T S Meiron et al.
Journal of food science, 72(9), E485-E491 (2007-11-24)
Food adhesion is an important attribute that could have both positive and negative ramifications depending on the application. Yet, its quantification remains cumbersome and as a consequence adhesion models are scarce. The effect of surface roughness, free energy, and ozone

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