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Merck
CN

00375

4-乙酰氨-2,2,6,6-四甲基哌啶-1-氧

greener alternative

purum, ≥98.0% (HPLC)

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关于此项目

经验公式(希尔记法):
C11H21N2O2
化学文摘社编号:
分子量:
213.30
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
423-840-3
Beilstein/REAXYS Number:
3546225
MDL number:
Assay:
≥98.0% (HPLC)
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grade

purum

Quality Segment

assay

≥98.0% (HPLC)

greener alternative product score

old score: 9
new score: 8
Find out more about DOZN™ Scoring

greener alternative product characteristics

Waste Prevention
Safer Solvents and Auxiliaries
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

143-145 °C (lit.), 143-146 °C

functional group

amide

greener alternative category

storage temp.

2-8°C

SMILES string

CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1

InChI

1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)

InChI key

UXBLSWOMIHTQPH-UHFFFAOYSA-N

General description

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by 1H, 13C and 15N NMR spectral data.
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives . This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Waste Prevention”, “Safer Solvents and Auxiliaries” and “Inherently Safer Chemistry for Accident Prevention”. Click here to view its DOZN scorecard.

Application

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.

Other Notes

将醇轻度氧化成羰基的新型氧化剂


pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

存储类别

11 - Combustible Solids

wgk

WGK 1

ppe

dust mask type N95 (US), Eyeshields, Gloves

flash_point_f

No data available

flash_point_c

No data available



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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