00375
4-乙酰氨-2,2,6,6-四甲基哌啶-1-氧
purum, ≥98.0% (HPLC)
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关于此项目
经验公式（希尔记法）:
C11H21N2O2
化学文摘社编号:
分子量:
213.30
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
423-840-3
Beilstein/REAXYS Number:
3546225
MDL number:
产品名称
4-乙酰氨-2,2,6,6-四甲基哌啶-1-氧, purum, ≥98.0% (HPLC)
InChI key
UXBLSWOMIHTQPH-UHFFFAOYSA-N
InChI
1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
SMILES string
CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
grade
purum
assay
≥98.0% (HPLC)
greener alternative product score
old score: 9
new score: 8
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greener alternative product characteristics
Waste Prevention
Safer Solvents and Auxiliaries
Inherently Safer Chemistry for Accident Prevention
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sustainability
Greener Alternative Product
mp
143-145 °C (lit.)
143-146 °C
functional group
amide
greener alternative category
storage temp.
2-8°C
Quality Level
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相关类别
Other Notes
将醇轻度氧化成羰基的新型氧化剂
Application
4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.
General description
4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by 1H, 13C and 15N NMR spectral data.
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Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Reaction of Nitroxides with Sulfur Containing Compounds II [1]. Preparation of Nitroxides Bearing an Isothiocyanate Substituent in View of the Nitroxyl Group Reduction with Thiophosgene.
Zakrzewski J, et al.
Monatshefte fur Chemie / Chemical Monthly, 134(6), 843-850 (2003)
A Koceva-Chyła et al.
Anticancer research, 20(6B), 4611-4618 (2001-02-24)
The novel nitroxyl, Tempicol-3 (nitroxide-N-oxide) was synthesized and its capacity to act as a scavenger of hydroxyl radicals was tested. The concentration-dependent reducibility of this novel compound was also examined and compared with those of previously characterized nitroxides, Tempo and
A 1H, 13C and 15N NMR study of oxidation and reduction products of 4-acetamido-2, 2, 6, 6-tetramethylpiperidine-1-oxyl.
Schilf W, et al.
Journal of Molecular Structure, 407(1), 1-3 (1997)
Z. Ma et al.
The Journal of Organic Chemistry, 56, 6110-6110 (1991)
D Metodiewa et al.
Biochemistry and molecular biology international, 42(6), 1261-1270 (1997-09-26)
A novel complex, Rutoxyl [rutin/4-acetamide-1-hydroxy-2,2,6,6-tetramethylpiperidinium] was synthesized and its structure and anticancer activity were investigated. The results reported here are consistent with our idea, that the formation of such a complex of two biologically active molecules: polyphenolic flavonoid antioxidant (Rutin)
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