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Merck
CN

00768

1-乙基-3-甲基咪唑四氟硼酸盐

for electrochemistry, ≥99.0% (HPLC)

别名:

EMIMBF4

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关于此项目

经验公式(希尔记法):
C6H11BF4N2
化学文摘社编号:
分子量:
197.97
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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产品名称

1-乙基-3-甲基咪唑四氟硼酸盐, for electrochemistry, ≥99.0% (HPLC)

InChI key

CUNYTRQQXKCRTJ-UHFFFAOYSA-N

SMILES string

F[B-](F)(F)F.CCn1cc[n+](C)c1

InChI

1S/C6H11N2.BF4/c1-3-8-5-4-7(2)6-8;2-1(3,4)5/h4-6H,3H2,1-2H3;/q+1;-1

assay

≥99.0% (HPLC)

form

liquid

impurities

≤200 ppm water

refractive index

n20/D 1.413 (lit.)

bp

>350 °C (lit.)

mp

15 °C (lit.)

density

1.294 g/mL at 25 °C (lit.)

anion traces

bromide (Br-): ≤10 mg/kg
chloride (Cl-): ≤10 mg/kg
nitrate (NO3-): ≤10 mg/kg
sulfate (SO42-): ≤10 mg/kg

Quality Level

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Application

1-乙基-3-甲基咪唑鎓四氟硼酸盐是室温离子液体,作为电解质,在电化学研究中广泛应用。目前已运用 NMR 技术对其扩散系数、 13C自旋晶格弛豫时间和核奥弗豪泽(Overhauser)增强效应进行分析,研究其氢键。同时在宽温范围内,对密度、粘度、热稳定性、表面张力、折射率和pH值等一些基本物理性质和化学性质进行了研究。

pictograms

Exclamation markEnvironment

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Physical and electrochemical properties of 1-alkyl-3-methylimidazolium tetrafluoroborate for electrolyte
Nishida T, et al.
Journal of Fluorine Chemistry, 120(2), 135-141 (2003)
NMR evidence of hydrogen bonding in 1-ethyl-3-methylimidazolium-tetrafluoroborate room temperature ionic liquid
Huang JF, et al.
Inorgorganica Chimica Acta, 320(1-2), 7-11 (2001)
Electrochemical study of copper in a basic 1-ethyl-3-methylimidazolium tetrafluoroborate room temperature molten salt
Chen PY and Sun IW
Electrochimica Acta, 45(3), 441-450 (1999)
The Room Temperature Ionic Liquid 1-Ethyl-3-methylimidazolium Tetrafluoroborate: Electrochemical Couples and Physical Properties.
Fuller J, et al.
Journal of the Electrochemical Society, 144(11), 3881-3886 (1997)
Sungwon Lee et al.
Nature communications, 5, 5898-5898 (2014-12-20)
To measure electrophysiological signals from the human body, it is essential to establish stable, gentle and nonallergic contacts between the targeted biological tissue and the electrical probes. However, it is difficult to form a stable interface between the two for

商品

Ionic Liquids serve as non-aqueous electrolytes in electrochemical applications, valued for their conductivity and stability.

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