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02300

D-(+)-苹果酸

Name: <SC>D-</SC>(+)-苹果酸
Brand: SIAL

unnatural form, ≥97.0% (T)

别名:

(R)-(+)-2-羟基琥珀酸, D-羟基丁二酸

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关于此项目

线性分子式:

HO₂CCH₂CH(OH)CO₂H

化学文摘社编号:

636-61-3

分子量:

134.09

UNSPSC Code:

51113400

NACRES:

NA.22

PubChem Substance ID:

329747411

EC Number:

211-262-2

Beilstein/REAXYS Number:

1723540

MDL number:

MFCD00004245

Assay:

≥97.0% (T)

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属性

Quality Level

200

assay

≥97.0% (T)

optical activity

[α]20/D +28.0±2°, c = 5.5% in pyridine

quality

unnatural form

mp

98-102 °C (lit.)

functional group

hydroxyl, carboxylic acid

SMILES string

O[C@H](CC(O)=O)C(O)=O

InChI

1S/C4H6O5/c5-2(4(8)9)1-3(6)7/h2,5H,1H2,(H,6,7)(H,8,9)/t2-/m1/s1

InChI key

BJEPYKJPYRNKOW-UWTATZPHSA-N

说明

Application

D-(+)-苹果酸可用于：

作为对映选择性全合成 (−)-erinapyrone B的起始材料。
作为从各种醛、苯胺和亚磷酸二乙酯合成α-氨基膦酸酯的手性有机催化剂。

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pictograms

GHS05,GHS07

signalword

Danger

hcodes

H315,H318,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Intestinal permeability, digestive stability and oral bioavailability of dietary small RNAs.

Jian Yang et al.

Scientific reports, 8(1), 10253-10253 (2018-07-08)

Impactful dietary RNA delivery requires improving uptake and enhancing digestive stability. In mouse feeding regimes, we have demonstrated that a plant-based ribosomal RNA (rRNA), MIR2911, is more bioavailable than synthetic MIR2911 or canonical microRNAs (miRNAs). Here mutagenesis was used to

Concise Total Synthesis of (-)-Erinapyrone B from D-(+)-Malic Acid

Samala R, et al.

Synthetic Communications, 44(4), 500-506 (2014)

(S)-9-(3-hydroxy-2-phosphonylmethoxypropyl)adenine [(S)-HPMPA]: a purine analogue with trypanocidal activity in vitro and in vivo.

R Kaminsky et al.

Tropical medicine & international health : TM & IH, 1(2), 255-263 (1996-04-01)

The unique features of purine salvage systems of pathogenic haemoflagellates render them selectively susceptible to the cytotoxic effects of purine analogues. A series of acyclic nucleoside phosphonates were evaluated for activity against pathogenic haemoflagellates in vitro. One of the phosphonylmethoxyalkylpurines

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