InChI key
OAICVXFJPJFONN-UHFFFAOYSA-N
InChI
1S/P
SMILES string
[P]
vapor density
0.02 (vs air)
vapor pressure
0.03 mmHg ( 21 °C), 1 mmHg ( 76.6 °C)
assay
≥97.0%
autoignition temp.
500 °F
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
resistivity
10 μΩ-cm, 20°C
mp
416 °C (subl.) (lit.)
density
2.34 g/mL at 25 °C (lit.)
cation traces
Fe: ≤2000 mg/kg
storage temp.
room temp
Quality Level
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General description
Red phosphorus is the most common allotrope of phosphorus due to its relative stability compared to white phosphorus. It has a variety of uses including, but not limited to, use as a catalyst, battery anode, flame retardant, and igniter.
Application
Red phosphorus can be used as a:
- Photocatalyst for the formation of H2 from water.
- Catalyst in the synthesis of tris(2-pyridyl)phosphine by reacting with 2-bromopyridine in the presence of a base.
- Flame retardant along with aluminum oxide in recycled poly(ethylene terephthalate).
- Anode material in combination with carbon composites for sodium-ion batteries.
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 3 - Flam. Sol. 2
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Red phosphorus: an elemental photocatalyst for hydrogen formation from water
Wang F, et al.
Applied Catalysis. B, Environmental, 111, 409-414 (2012)
New Evidence Concerning the Structure of Amorphous Red Phosphorus
Hartl H
Angewandte Chemie (International Edition in English), 34(23-24), 2637-2638 (1996)
Expedient one-pot organometallics-free synthesis of tris (2-pyridyl) phosphine from 2-bromopyridine and elemental phosphorus
Trofimov BA, et al.
Tetrahedron Letters, 53(19), 2424-2427 (2012)
An amorphous red phosphorus/carbon composite as a promising anode material for sodium ion batteries
Kim Y, et al.
Advanced Materials, 25(22), 3045-3049 (2013)
Red phosphorus/aluminium oxide compositions as flame retardants in recycled poly (ethylene terephthalate
Laoutid F, et al.
Polymer Degradation and Stability, 82(2), 357-363 (2003)
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