04365
1-乙基-3-甲基咪唑四氟硼酸盐
≥97.0% (HPLC/T)
别名:
EMIMBF4
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选择尺寸
关于此项目
经验公式（希尔记法）:
C6H11BF4N2
化学文摘社编号:
分子量:
197.97
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
≥97.0% (HPLC/T)
Bp:
>350 °C (lit.)
产品名称
1-乙基-3-甲基咪唑四氟硼酸盐, ≥97.0% (HPLC/T)
InChI
1S/C6H11N2.BF4/c1-3-8-5-4-7(2)6-8;2-1(3,4)5/h4-6H,3H2,1-2H3;/q+1;-1
SMILES string
F[B-](F)(F)F.CCn1cc[n+](C)c1
InChI key
CUNYTRQQXKCRTJ-UHFFFAOYSA-N
assay
≥97.0% (HPLC/T)
form
liquid
refractive index
n20/D 1.41
n20/D 1.413 (lit.)
bp
>350 °C (lit.)
mp
15 °C (lit.)
density
1.294 g/mL at 25 °C (lit.)
Quality Level
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Application
可以使用1-乙基-3-甲基咪唑四氟硼酸盐作为反应介质，进行高苯丙氨酸酯的酶促拆分以形成对映体高苯丙氨酸。
General description
1-乙基-3-甲基咪唑四氟硼酸盐是一种室温离子液体 (RTIL)。
Other Notes
空气和水稳定性液体电解质 (m.p. 15°C)
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Enzymatic Reactions in Ionic Liquids
Aldrich Chemfiles, 5(6) null
Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids.
J.S. Wilkes et al.
Journal of the Chemical Society. Chemical Communications, 13, 965-965 (1992)
Crystal structures of frozen room temperature ionic liquids, 1-ethyl-3-methylimidazolium tetrafluoroborate (EMImBF 4), hexafluoroniobate (EMImNbF 6) and hexafluorotantalate (EMImTaF 6), determined by low-temperature X-ray diffraction
Matsumoto, Kazuhiko, et al.
Solid State Sciences, 8.10, 1250-1257 (2006)
Density and Viscosity Measurements for Binary Mixtures of 1-Ethyl-3-methylimidazolium Tetrafluoroborate ([Emim][BF4]) with Dimethylacetamide, Dimethylformamide, and Dimethyl Sulfoxide
Fan, Xian-Heng, Yan-Ping Chen, and Chie-Shaan Su.
Journal of Chemical and Engineering Data, 61.2, 920-927 (2016)
Efficient, halide free synthesis of new, low cost ionic liquids: 1, 3-dialkylimidazolium salts containing methyl-and ethyl-sulfate anions
Holbrey, John D., et al.
Green Chemistry, 4.5, 407-413 (2002)
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