04367
1-乙基-3-甲基咪唑三氟甲磺酸盐
≥98.0% (T)
别名:
[EMIM] [TRIFLATE], EMIM Otf
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关于此项目
经验公式（希尔记法）:
C7H11F3N2O3S
化学文摘社编号:
分子量:
260.23
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
≥98.0% (T)
Bp:
>350 °C (lit.)
InChI
1S/C6H11N2.CHF3O3S/c1-3-8-5-4-7(2)6-8;2-1(3,4)8(5,6)7/h4-6H,3H2,1-2H3;(H,5,6,7)/q+1;/p-1
SMILES string
CCn1cc[n+](C)c1.[O-]S(=O)(=O)C(F)(F)F
InChI key
ZPTRYWVRCNOTAS-UHFFFAOYSA-M
assay
≥98.0% (T)
form
liquid
impurities
≤0.1% water
refractive index
n20/D 1.435 (lit.), n20/D 1.435
bp
>350 °C (lit.)
density
1.387 g/mL at 25 °C (lit.)
functional group
fluoro, triflate
Quality Level
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Application
1-乙基-3-甲基咪唑鎓三氟甲磺酸盐可作为溶剂，生产离子型聚合物-聚合物复合材料（IP2C），以及用于在脂肪酶催化的4-戊烯酸对映选择性胺的酰化反应中。
Other Notes
对空气和水均稳定的离子液体，可用于电化学用途（熔盐技术），所呈现的电化学稳定性窗口 ≥4V，并且在高达 350°C 下仍稳定
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
425.3 °F - closed cup
flash_point_c
218.5 °C - closed cup
ppe
Eyeshields, Gloves
E.I. Cooper et al.
Proc. Electrochem. Soc., 16, 386-386 (1992)
Capillary electrophoretic application of 1-alkyl-3-methylimidazolium-based ionic liquids
Yanes, Enrique G., et al.
Analytical Chemistry, 73.16, 3838-3844 (2001)
Heat capacities and excess enthalpies of 1-ethyl-3-methylimidazolium-based ionic liquids and water
Ficke, Lindsay E., He?ctor Rodri?guez, and Joan F. Brennecke
Journal of Chemical and Engineering Data, 53.9, 2112-2119 (2008)
A study on IP2C actuators using ethylene glycol or EmI-Tf as solvent.
Di Pasquale G, et al.
Smart Materials and Structures, 20(4), 045014-045014 (2011)
Ion-pair structure of vaporized ionic liquid studied by matrix-isolation FTIR spectroscopy with DFT calculations: A case of 1-ethyl-3-methylimidazolium trifluoromethanesulfonate
Akai, Nobuyuki, Akio Kawai, and Kazuhiko Shibuya
The Journal of Physical Chemistry A, 114.48, 12662-12666 (2010)
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