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06061

烯丙基苯砜

Name: 烯丙基苯砜
Brand: SIAL

purum, ≥98.0% (GC)

别名:

(2-Propen-1-ylsulfonyl)benzene, (2-Propenylsulfonyl)benzene, (Allylsulfonyl)benzene, Phenyl 2-propenyl sulfone

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关于此项目

线性分子式:

C₆H₅SO₂CH₂CH=CH₂

化学文摘社编号:

16212-05-8

分子量:

182.24

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

329748204

EC Number:

240-338-8

Beilstein/REAXYS Number:

1863561

MDL number:

MFCD00014739

Assay:

≥98.0% (GC)

Form:

liquid

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属性

grade

purum

Quality Level

200

assay

≥98.0% (GC)

form

liquid

refractive index

n20/D 1.548

bp

110-113 °C/0.5 mmHg (lit.)

density

1.189 g/mL at 25 °C (lit.)

functional group

sulfone

storage temp.

2-8°C

SMILES string

C=CCS(=O)(=O)c1ccccc1

InChI

1S/C9H10O2S/c1-2-8-12(10,11)9-6-4-3-5-7-9/h2-7H,1,8H2

InChI key

KYPIULIVYSQNNT-UHFFFAOYSA-N

说明

Application

Possible usages of allyl phenyl sulfone:

It can undergo isomerization by the nonionic proazaphosphatrane catalysts under mild reaction conditions.
It can react with epoxymesylate to give cycloalkane derivative. This method has been employed in the synthesis of marine eicosanoid bacillariolides I-III.
It can undergo electrocatalytic additions to vinyl sulfones catalyzed by an electrogenerated base.

Starting material for the preparation of 1-alkyl-2-methylethenes; Michael additions to enones; Synthesis of α,β-unsaturated nitriles

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pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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M. Hirama

Tetrahedron Letters, 22, 1905-1905 (1981)

Proazaphosphatrane P (RNCH2CH2) 3N (R= Me, i?Pr)?Catalyzed Isomerization of Allylaromatics, Allyl Phenyl Sulfide, Allyl Phenyl Sulfone, and bis?Allylmethylene Double Bond?Containing Compounds

Yu Z, et al.

Advanced Synthesis & Catalysis, 348(1?2), 111-117 (2006)

One-Pot Synthesis of Cycloalkane Derivatives using Allyl Phenyl Sulfone and Epoxymesylate.

Miyaoka H, et al.

Tetrahedron, 56(41), 8077-8081 (2000)

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全球贸易项目编号

货号	GTIN
143847-10G	04061838735188
143847-50G	04061838735195
06061-50ML	04061837253805
06061-10ML	04061837253799