06061
烯丙基苯砜
purum, ≥98.0% (GC)
别名:
(2-Propen-1-ylsulfonyl)benzene, (2-Propenylsulfonyl)benzene, (Allylsulfonyl)benzene, Phenyl 2-propenyl sulfone
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关于此项目
线性分子式:
C6H5SO2CH2CH=CH2
化学文摘社编号:
分子量:
182.24
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
240-338-8
Beilstein/REAXYS Number:
1863561
MDL number:
产品名称
烯丙基苯砜, purum, ≥98.0% (GC)
InChI key
KYPIULIVYSQNNT-UHFFFAOYSA-N
InChI
1S/C9H10O2S/c1-2-8-12(10,11)9-6-4-3-5-7-9/h2-7H,1,8H2
SMILES string
C=CCS(=O)(=O)c1ccccc1
grade
purum
assay
≥98.0% (GC)
form
liquid
refractive index
n20/D 1.548 (lit.)
n20/D 1.548
bp
110-113 °C/0.5 mmHg (lit.)
density
1.189 g/mL at 25 °C (lit.)
functional group
sulfone
storage temp.
2-8°C
Quality Level
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Application
Possible usages of allyl phenyl sulfone:
- It can undergo isomerization by the nonionic proazaphosphatrane catalysts under mild reaction conditions.
- It can react with epoxymesylate to give cycloalkane derivative. This method has been employed in the synthesis of marine eicosanoid bacillariolides I-III.
- It can undergo electrocatalytic additions to vinyl sulfones catalyzed by an electrogenerated base.
Starting material for the preparation of 1-alkyl-2-methylethenes; Michael additions to enones; Synthesis of α,β-unsaturated nitriles
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
One-Pot Synthesis of Cycloalkane Derivatives using Allyl Phenyl Sulfone and Epoxymesylate.
Miyaoka H, et al.
Tetrahedron, 56(41), 8077-8081 (2000)
M. Hirama
Tetrahedron Letters, 22, 1905-1905 (1981)
Proazaphosphatrane P (RNCH2CH2) 3N (R= Me, i?Pr)?Catalyzed Isomerization of Allylaromatics, Allyl Phenyl Sulfide, Allyl Phenyl Sulfone, and bis?Allylmethylene Double Bond?Containing Compounds
Yu Z, et al.
Advanced Synthesis & Catalysis, 348(1?2), 111-117 (2006)
D. Savoia et al.
Journal of the Chemical Society. Perkin Transactions 1, 123-123 (1977)
D.F. Taber et al.
The Journal of Organic Chemistry, 46, 4817-4817 (1981)
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