06357
(S)-4-苄基噻唑啉-2-硫酮
≥95.0% (GC)
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选择尺寸
关于此项目
经验公式（希尔记法）:
C10H11NS2
化学文摘社编号:
分子量:
209.33
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
(S)-4-苄基噻唑啉-2-硫酮, ≥95.0% (GC)
InChI key
SLDUGQISGRPGAW-VIFPVBQESA-N
SMILES string
S=C1N[C@H](CS1)Cc2ccccc2
InChI
1S/C10H11NS2/c12-10-11-9(7-13-10)6-8-4-2-1-3-5-8/h1-5,9H,6-7H2,(H,11,12)/t9-/m0/s1
assay
≥95.0% (GC)
optical activity
[α]20/D -122±5°, c = 1% in chloroform
optical purity
enantiomeric ratio: ≥99:1 (LC)
functional group
phenyl
thioether
Quality Level
Application
具有高度选择性和有效性的手性助剂，与二异丁基氢化铝发生还原裂解反应可直接还原为相应的醛和手性助剂。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Velazquez. F.; Olivo, H. F.
Current Organic Chemistry, 6, 303-303 (2002)
M T Crimmins et al.
Organic letters, 2(6), 775-777 (2001-02-07)
[formula: see text] Asymmetric aldol additions using chlorotitanium enolates of thiazolidinethione propionates proceed with high diastereoselectivity for the "Evans" or "non-Evans" syn product depending on the nature and amount of the base used. With (-)-sparteine as the base, selectivities of
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