09587
第一代Grubbs催化剂®
purum, ≥97.0% (C)
别名:
Grubbs催化剂® C823, 双(三环己基膦)亚苄基钌(IV)二氯化物, 苯基亚甲基双(三环己基磷)二氯化钌, 苯基亚甲基双(三环己基膦)二氯化钌
InChI key
IEEOQDKBWLBRKR-UHFFFAOYSA-L
InChI
1S/2C18H33P.C8H8.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-8-6-4-3-5-7-8;;;/h2*16-18H,1-15H2;2-7H,1H2;2*1H;/q;;;;;+2/p-2
SMILES string
Cl[Ru]Cl.C=Cc1ccccc1.C2CCC(CC2)P(C3CCCCC3)C4CCCCC4.C5CCC(CC5)P(C6CCCCC6)C7CCCCC7
grade
purum
assay
≥97.0% (C)
mp
153 °C (dec.) (lit.)
storage temp.
2-8°C
Other Notes
用于各种复分解反应的高效催化剂
Legal Information
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG
法规信息
新产品
此项目有
P. Schwab et al.
Journal of the American Chemical Society, 118, 100-100 (1996)
A. Furstner et al.
Journal of the American Chemical Society, 119, 9130-9130 (1997)
T M Trnka et al.
Accounts of chemical research, 34(1), 18-29 (2001-02-15)
In recent years, the olefin metathesis reaction has attracted widespread attention as a versatile carbon-carbon bond-forming method. Many new applications have become possible because of major advances in catalyst design. State-of-the-art ruthenium catalysts are not only highly active but also
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