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Merck
CN

11223

3,3′,5,5′-四溴双酚 A

greener alternative

analytical standard

别名:

4,4′-异亚丙基双(2,6-二溴苯酚), TBBPA

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关于此项目

线性分子式:
(CH3)2C[C6H2(Br)2OH]2
化学文摘社编号:
分子量:
543.87
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
201-236-9
Beilstein/REAXYS Number:
1889048
MDL number:
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InChI

1S/C15H12Br4O2/c1-15(2,7-3-9(16)13(20)10(17)4-7)8-5-11(18)14(21)12(19)6-8/h3-6,20-21H,1-2H3

InChI key

VEORPZCZECFIRK-UHFFFAOYSA-N

SMILES string

CC(C)(c1cc(Br)c(O)c(Br)c1)c2cc(Br)c(O)c(Br)c2

grade

analytical standard

assay

≥97% (HPLC), 96.5-103.5% (wt.)

shelf life

limited shelf life, expiry date on the label

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

mp

177-183 °C

Quality Level

application(s)

environmental

format

neat

greener alternative category

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General description

3,3′,5,5′-四溴双酚A是双酚A的溴化衍生物,通常用作阻燃剂。它在各种消费品中都有应用,从织物到塑料和电子产品。据报道,使用环境友好型壳聚糖(CS)/聚乙烯醇(PVA)纳米纤维膜将其从水生环境中去除。
This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)

Application

3,3′,5,5′-四溴双酚A可用作分析参考标准品,用于通过色谱技术对空气样品和沉积物/污泥样品中的分析物进行定量。
有关合适的仪器技术的更多信息,请参阅产品的分析证书。想要获得更多支持,请联系技术服务部。

Packaging

无底玻璃瓶。内含物装在插入的融合锥内。

pictograms

Health hazardEnvironment

wgk

WGK 2

signalword

Danger

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

flash_point_f

No data available

flash_point_c

No data available


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Zhiyong Xie et al.
Analytica chimica acta, 584(2), 333-342 (2007-03-28)
A simple and effective method has been developed for analysis of the flame retardant tetrabromobisphenol A (TBBPA) in environmental samples by using modified soxhlet extraction in combination with silica gel clean-up, derivatization with silylation reagent and gas chromatography-mass spectrometry (GC-MS)
An-Hong Feng et al.
Marine pollution bulletin, 64(5), 919-925 (2012-04-06)
Hexabromocyclododecane (HBCD) and tetrabromobisphenol A (TBBPA) were measured in surface sediments in the Pearl River Delta, southern China. The concentrations ranged from 0.06 to 304 ng/g dry weight for TBBPA and from 0.03 to 31.6 ng/g for total HBCD. The
Un-Jung Kim et al.
Environmental pollution (Barking, Essex : 1987), 184, 193-200 (2013-09-26)
The concentrations of tetrabromobisphenol A (TBBPA) and hexabromocyclododecanes (HBCDs), and their correlations with thyroid hormones, were investigated in sera from 26 infants with congenital hypothyroidism, 12 healthy infants, and their mothers. The analyte concentrations were not significantly different in the
Xiaoyu Zhou et al.
Journal of hazardous materials, 246-247, 96-102 (2013-01-08)
Leaching assessment on five heavy metals (copper, zinc, lead, nickel and cadmium) and two brominated flame retardants (BFRs), polybrominated diphenyl ethers (PBDEs) and tetrabromobisphenol A (TBBPA), from waste printed circuit boards (WPCBs) were conducted using various leaching methods. The mean
Shaogang Chu et al.
Journal of chromatography. A, 1097(1-2), 25-32 (2005-11-22)
A high performance liquid chromatography-electrospray (negative) ionization-tandem mass spectrometry (HPLC-ESI(-)-MS-MS) based method has been developed for simultaneous determination of bisphenol A (BPA), tetrachlorobisphenol A (TCBPA), and tetrabromobisphenol A (TBBPA), as well as lower brominated BPA analogues in sediment and sludge

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