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Merck
CN

11223

Supelco

3,3′,5,5′-四溴双酚 A

greener alternative

analytical standard

别名:

4,4′-异亚丙基双(2,6-二溴苯酚), TBBPA

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关于此项目

线性分子式:
(CH3)2C[C6H2(Br)2OH]2
化学文摘社编号:
分子量:
543.87
Beilstein:
1889048
EC 号:
MDL编号:
UNSPSC代码:
41116107
PubChem化学物质编号:
NACRES:
NA.24
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等级

analytical standard

质量水平

方案

≥97% (HPLC)
96.5-103.5% (wt.)

保质期

limited shelf life, expiry date on the label

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

技术

HPLC: suitable
gas chromatography (GC): suitable

mp

177-183 °C
178-181 °C (lit.)

应用

environmental

包装形式

neat

环保替代产品分类

SMILES字符串

CC(C)(c1cc(Br)c(O)c(Br)c1)c2cc(Br)c(O)c(Br)c2

InChI

1S/C15H12Br4O2/c1-15(2,7-3-9(16)13(20)10(17)4-7)8-5-11(18)14(21)12(19)6-8/h3-6,20-21H,1-2H3

InChI key

VEORPZCZECFIRK-UHFFFAOYSA-N

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一般描述

3,3′,5,5′-四溴双酚A是双酚A的溴化衍生物,通常用作阻燃剂。它在各种消费品中都有应用,从织物到塑料和电子产品。据报道,使用环境友好型壳聚糖(CS)/聚乙烯醇(PVA)纳米纤维膜将其从水生环境中去除。
This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)

应用

3,3′,5,5′-四溴双酚A可用作分析参考标准品,用于通过色谱技术对空气样品和沉积物/污泥样品中的分析物进行定量。
有关合适的仪器技术的更多信息,请参阅产品的分析证书。想要获得更多支持,请联系技术服务部。

包装

无底玻璃瓶。内含物装在插入的融合锥内。

象形图

Health hazardEnvironment

警示用语:

Warning

危险声明

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Zhiyong Xie et al.
Analytica chimica acta, 584(2), 333-342 (2007-03-28)
A simple and effective method has been developed for analysis of the flame retardant tetrabromobisphenol A (TBBPA) in environmental samples by using modified soxhlet extraction in combination with silica gel clean-up, derivatization with silylation reagent and gas chromatography-mass spectrometry (GC-MS)
Terminal elimination half-lives of the brominated flame retardants TBBPA, HBCD, and lower brominated PBDEs in humans.
Geyer, Harald J., et al.
Organohalogen compounds, 66, 3867-3872 (2004)
An environmentally-friendly enzyme-based nanofibrous membrane for 3, 3?, 5, 5?-tetrabromobisphenol removal
Xu R, et al.
Royal Society of Chemistry Advances, 5(79), 64091-64097 (2015)
An-Hong Feng et al.
Marine pollution bulletin, 64(5), 919-925 (2012-04-06)
Hexabromocyclododecane (HBCD) and tetrabromobisphenol A (TBBPA) were measured in surface sediments in the Pearl River Delta, southern China. The concentrations ranged from 0.06 to 304 ng/g dry weight for TBBPA and from 0.03 to 31.6 ng/g for total HBCD. The
Un-Jung Kim et al.
Environmental pollution (Barking, Essex : 1987), 184, 193-200 (2013-09-26)
The concentrations of tetrabromobisphenol A (TBBPA) and hexabromocyclododecanes (HBCDs), and their correlations with thyroid hormones, were investigated in sera from 26 infants with congenital hypothyroidism, 12 healthy infants, and their mothers. The analyte concentrations were not significantly different in the

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