11291
1-乙基-3-甲基咪唑啉双(三氟甲基磺酰基)亚胺
≥97.0% (NMR)
别名:
EMIM BTI, EMIM TFSI, EMIMIm
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关于此项目
经验公式（希尔记法）:
C8H11F6N3O4S2
化学文摘社编号:
分子量:
391.31
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
1-乙基-3-甲基咪唑啉双(三氟甲基磺酰基)亚胺, ≥97.0% (NMR)
InChI
1S/C6H11N2.C2F6NO4S2/c1-3-8-5-4-7(2)6-8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h4-6H,3H2,1-2H3;/q+1;-1
SMILES string
CCn1cc[n+](C)c1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F
InChI key
LRESCJAINPKJTO-UHFFFAOYSA-N
assay
≥97.0% (NMR)
form
liquid
impurities
<0.5% water
mp
≥−15 °C (lit.)
functional group
fluoro
Quality Level
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Application
[EMIM] [N（TF）2]在微波条件下，可以用作合成氧化锌（ZnO）纳米颗粒的绿色溶剂。它适用于需要具有高CO2溶解度的溶剂的反应。
General description
1-乙基-3-甲基咪唑双（三氟甲基磺酰基）酰亚胺[EMIM] [N（Tf）2]是一种室温离子液体（RTIL）。（[EMIM] [N（TF）2]）作为非水溶剂，由于其具有低蒸气压、高热稳定性、良好的导电性和宽的电化学窗口，因此在电活性物质的电化学研究中优于传统的非质子极性有机溶剂。[EMIM] [N（TF）2]在CO2中显示出良好的溶解性。
Legal Information
产品受美国专利 5,827,602 保护，转让给 Covalent Associates, Inc. Woburn, Ma, USA
Other Notes
在离子液体中进行对映选择性反应
Physical form
疏水性氟化离子液体
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 1
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Determination of ammonia based on the electro-oxidation of hydroquinone in dimethylformamide or in the room temperature ionic liquid, 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide.
Giovanelli D, et al.
Talanta, 62(5), 904-911 (2004)
Voltammetry of oxygen in the room-temperature ionic liquids 1-ethyl-3-methylimidazolium bis ((trifluoromethyl) sulfonyl) imide and hexyltriethylammonium bis ((trifluoromethyl) sulfonyl) imide: one-electron reduction to form superoxide. Steady-state and transient behavior in the same cyclic voltammogram resulting from widely different diffusion coefficients of oxygen and superoxide
Buzzeo, Marisa C., et al.
The Journal of Physical Chemistry A, 107.42, 8872-8878 (2003)
Pedro Lozano et al.
Chemical communications (Cambridge, England), (7), 692-693 (2002-07-18)
Soluble Candida antarctica lipase B dissolved in ionic liquids showed good synthetic activity, enantioselectivity and operational stability in supercritical carbon dioxide for both butyl butyrate synthesis and the kinetic resolution of 1-phenylethanol processes by transesterification.
Investigation on physical and electrochemical properties of three imidazolium based ionic liquids (1-hexyl-3-methylimidazolium tetrafluoroborate, 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide and 1-butyl-3-methylimidazolium methylsulfate)
Beigi, Ali Akbar Miran, et al.
Journal of Molecular Liquids, 177, 361-368 (2013)
J.M. Fraile et al.
Tetrahedron Asymmetry, 12, 1891-1891 (2001)
商品
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