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Merck
CN

125431

环己烯

inhibitor-free, ReagentPlus®, 99%

别名:

四氢化苯

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关于此项目

经验公式(希尔记法):
C6H10
化学文摘社编号:
分子量:
82.14
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-807-8
Beilstein/REAXYS Number:
906737
MDL number:
Assay:
99%
Bp:
83 °C (lit.)
Vapor pressure:
160 mmHg ( 20 °C)
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vapor density

2.8 (vs air)

Quality Level

vapor pressure

160 mmHg ( 20 °C)

product line

ReagentPlus®

assay

99%

form

liquid

autoignition temp.

590 °F

expl. lim.

5 %

dilution

(for general lab use)

refractive index

n20/D 1.446 (lit.)

bp

83 °C (lit.)

mp

−104 °C (lit.)

solubility

water: insoluble

density

0.811 g/mL at 25 °C (lit.)

SMILES string

C1CCC=CC1

InChI

1S/C6H10/c1-2-4-6-5-3-1/h1-2H,3-6H2

InChI key

HGCIXCUEYOPUTN-UHFFFAOYSA-N

General description

Cyclohexene is a cyclic alkene. Kinetics of its reaction with hydrogen in gas and liquid phases over different palladium catalysts supported on silica gel and alumina (temperature range = 264 to 308K and hydrogen pressures = 4 to 89kPa) was investigated. Cyclohexene is formed during the batch-wise partial hydrogenation of benzene over ruthenium catalysts in the presence of an aqueous zinc sulphate solution. Cyclohexene undergoes enantioselective catalytic oxidation in the presence of hydrogen peroxide over environment-friendly peroxytungstate-organic complex catalysts to afford adipic acid. Selective hydrogenation of benzene has been reported to afford cyclohexene. It is an important precursor for the preparation of various chemicals such as cyclohexanol, cyclohexene hydroperoxide, etc.

Application

Cyclohexene has been used to investigate the kinetics of its liquid-phase hydrogenation reaction in the presence of Pd-Al catalyst supported on biomorphic carbon. It may be used for the industrial preparation of cyclohexanol.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

1.4 °F

flash_point_c

-17 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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Yuan Fang et al.
The journal of physical chemistry letters, 10(3), 468-473 (2019-01-03)
The adsorption of limonene, a common organic compound found in indoor air, on hydrophilic surfaces such as glass (SiO2), a prevalent surface in the indoor environment, is poorly understood. In this study, we have investigated the interaction of limonene and
Kinetics of liquid phase cyclohexene hydrogenation on Pd-Al/biomorphic carbon catalysts.
Caza?a F, et al.
Catalysis Today, 14-14 (2014)
Hydration of cyclohexene with solid acid catalysts.
Zhang H, et al.
Chemical Engineering Science, 57(2), 315-322 (2002)



全球贸易项目编号

货号GTIN
125431-2.5L04061838723567
125431-100ML04061838723543
125431-PZ04061826597170
125431-500ML04061838723574
125431-1L04061838723550