125903
1,3-二溴丙烷
99%, liquid, ReagentPlus®
别名:
三亚甲基二溴
产品名称
1,3-二溴丙烷, ReagentPlus®, 99%
蒸汽密度
7 (vs air)
质量水平
产品线
ReagentPlus®
方案
99%
表单
liquid
折射率
n20/D 1.524 (lit.)
沸点
167 °C (lit.)
mp
−34 °C (lit.)
密度
1.989 g/mL at 25 °C (lit.)
SMILES字符串
BrCCCBr
InChI
1S/C3H6Br2/c4-2-1-3-5/h1-3H2
InChI key
VEFLKXRACNJHOV-UHFFFAOYSA-N
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一般描述
1,3-二溴丙烷是一种二卤代丙烷。在碳电极表面的聚合物膜中，它分别被电生液相镍 (I) 手性和镍 (I) 手性催化还原生成环丙烷和丙烯。
应用
1,3-二溴丙烷可用于制备手性孪生双阳离子离子液体 和 1,3-双（1-7′-氯-4-喹啉基-4-哌嗪基）丙烷。3
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Warning
危险分类
Acute Tox. 4 Oral - Aquatic Chronic 2 - Flam. Liq. 3 - Skin Irrit. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
129.2 °F - closed cup
闪点(°C)
54 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Catalytic reduction of α,ω-dihaloalkanes with nickel (I) salen as a homogeneous-phase and polymer-bound mediator.
Dahm CE and Peters DG.
Journal of Electroanalytical Chemistry, 406(1), 119-129 (1996)
Synthesis of Chiral Geminal Dicationic Ionic Liquid from Amino Acids.
Yin A, et al.
Asian Journal of Chemistry, 25(12), 6721-6721 (2013)
S P James et al.
Toxicology letters, 8(1-2), 7-15 (1981-04-01)
Oral administration of 1,3-dibromopropane (2 mmol/kg) to rats resulted in a marked decrease in the level of hepatic glutathione (GSH). Sulphur-containing [14C]-metabolites were excreted in the bile of rats dose with 1,3-bromo[14C]propane and were subjected to enterohepatic cycling. After an
A Witkowski et al.
The Journal of biological chemistry, 267(26), 18488-18492 (1992-09-15)
Thioesterase II is a 29-kDa monomer which, in certain specialized tissues, acts as a chain terminator in fatty acid synthesis by hydrolyzing medium-chain fatty acids from the fatty acid synthase. As with serine proteases, hydrolysis appears to involve acylation of
Sang Kyu Lee et al.
Journal of toxicology and environmental health. Part A, 70(15-16), 1381-1390 (2007-07-27)
To determine a possible role of glutathione (GSH) conjugation in 1,3-dibromopropane (1,3-DBP)-induced hepatotoxicity and immunotoxicity, female BALB/c mice were treated orally with 1,3-DBP. Based on the liquid chromatography/electrospray ionization-tandem mass spectrometry (LC/ESI-MS) analyses, two forms of S-bromopropyl GSH were observed
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