14765
醋酸铊(I)
≥97.0%, solid
别名:
乙酸 铊(I) 盐
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关于此项目
线性分子式:
CH3COOTl
化学文摘社编号:
分子量:
263.43
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
209-257-5
MDL number:
Beilstein/REAXYS Number:
3693914
产品名称
醋酸铊(I), purum, ≥97.0%
InChI key
HQOJMTATBXYHNR-UHFFFAOYSA-M
InChI
1S/C2H4O2.Tl/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
SMILES string
CC(=O)O[Tl]
grade
purum
assay
≥97.0%
form
solid
reaction suitability
core: thallium
reagent type: catalyst
Quality Level
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Application
- Thallium Use: An Overview: Offers a comprehensive overview of Thallium(I) acetate′s use in organic synthesis in the oxidation of olefins and hydrocarbons, and in epoxidation and polymerization reactions (Genchi et al., 2021).
General description
Thallium (I) acetate functions as a catalyst to enhance the rate of chemical reactions in the synthesis of isothiocyanates from isocyanides and disulfides. In addition, it is also used as the source of thallium ions in organic solvents for electrochemical reactions.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
法规信息
铊类化学品
危险化学品
此项目有
Grigg, R.; Kennewell, P. et al
Tetrahedron Letters, 33, 7789-7789 (1992)
Electrochemical Behavior of Thallium Ion in Organic Solvents and its Application to Organic Synthesis
Tanabe T, et al.
ECS Transactions, 13(20), 7-7 (2008)
Thies, R.W.; Boop, J. L. et al
The Journal of Organic Chemistry, 48, 2021-2021 (1983)
The thallium (I) salt-catalyzed formation of isothiocyanates from isocyanides and disulfides
Tanaka S, et al.
Bulletin of the Chemical Society of Japan, 50(10), 2785-2788 (1977)
R Barroso-Moguel et al.
Toxicology, 89(1), 15-24 (1994-03-25)
Rats were treated with a single dose of thallium acetate (32 mg/kg i.p.) and the antidotal effect of D-penicillamine and prussian blue given alone or in combination was assessed by means of evaluation of the thallium-induced cerebellar histological lesions. After
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