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Merck
CN

14765

醋酸铊(I)

≥97.0%, solid

别名:

乙酸 铊(I) 盐

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关于此项目

线性分子式:
CH3COOTl
化学文摘社编号:
分子量:
263.43
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
209-257-5
MDL number:
Beilstein/REAXYS Number:
3693914
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产品名称

醋酸铊(I), purum, ≥97.0%

grade

purum

Quality Level

assay

≥97.0%

form

solid

reaction suitability

core: thallium, reagent type: catalyst

SMILES string

CC(=O)O[Tl]

InChI

1S/C2H4O2.Tl/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1

InChI key

HQOJMTATBXYHNR-UHFFFAOYSA-M

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General description

Thallium (I) acetate functions as a catalyst to enhance the rate of chemical reactions in the synthesis of isothiocyanates from isocyanides and disulfides. In addition, it is also used as the source of thallium ions in organic solvents for electrochemical reactions.

Application

  • Thallium Use: An Overview: Offers a comprehensive overview of Thallium(I) acetate′s use in organic synthesis in the oxidation of olefins and hydrocarbons, and in epoxidation and polymerization reactions (Genchi et al., 2021).

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

法规信息

铊类化学品
危险化学品

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分析证书(COA)

Lot/Batch Number

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Thies, R.W.; Boop, J. L. et al
The Journal of Organic Chemistry, 48, 2021-2021 (1983)
The thallium (I) salt-catalyzed formation of isothiocyanates from isocyanides and disulfides
Tanaka S, et al.
Bulletin of the Chemical Society of Japan, 50(10), 2785-2788 (1977)
Electrochemical Behavior of Thallium Ion in Organic Solvents and its Application to Organic Synthesis
Tanabe T, et al.
ECS Transactions, 13(20), 7-7 (2008)
Grigg, R.; Kennewell, P. et al
Tetrahedron Letters, 33, 7789-7789 (1992)
M Csicsaky et al.
Toxicology, 49(1), 121-129 (1988-04-01)
The toxic effect of thallium added to the bath solution was studied with intra- and extracellular recordings from mammalian nerve-muscle preparations. To elucidate the target region, 3 different functional parameters were studied: (1) Post-synaptic endplate potentials (EPPs) resulting from evoked

全球贸易项目编号

货号GTIN
14765-25G04061833416563
14765-100G04061833380499

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