14795
N,N,N′,N′-四甲基-1,8-萘二胺
purum, ≥99.0% (NT)
别名:
1,8-双二甲氨基萘, DMAN, Proton-sponge®
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关于此项目
经验公式（希尔记法）:
C14H18N2
化学文摘社编号:
分子量:
214.31
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
244-001-6
Beilstein/REAXYS Number:
396782
MDL number:
Assay:
≥99.0% (NT)
Form:
solid
InChI key
GJFNRSDCSTVPCJ-UHFFFAOYSA-N
InChI
1S/C14H18N2/c1-15(2)12-9-5-7-11-8-6-10-13(14(11)12)16(3)4/h5-10H,1-4H3
SMILES string
CN(C)c1cccc2cccc(N(C)C)c12
grade
purum
assay
≥99.0% (NT)
form
solid
mp
45-49 °C
functional group
amine
Quality Level
Application
N，N，N′，N′-四甲基-1，8-萘二胺用于多电荷寡核苷酸阴离子的质子化。它用作硝酸铋催化苯甲醛与乙酸酐反应的试剂。在液-液萃取法发酵液中有机酸分离过程中用作萃取剂。
Other Notes
具有独特性质的胺类强碱（"质子海绵"）
Legal Information
Proton-sponge is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Bismuth compounds in organic synthesis. Bismuth nitrate catalyzed chemoselective synthesis of acylals from aromatic aldehydes.
Aggen DH, et al.
Tetrahedron, 60(16), 3675-3679 (2004)
R.W. Alder et al.
Journal of the Chemical Society. Chemical Communications, 723-723 (1968)
Extractant screening for liquid-liquid extraction in environmentally benign production routes.
Krzyzaniak A, et al.
Chemical Engineering Transactions, 24, 709-714 (2011)
R.L. Benoit et al.
Canadian Journal of Chemistry, 65, 996-996 (1987)
Yu Xia et al.
Analytical chemistry, 77(11), 3683-3689 (2005-06-01)
A single sonic spray source has been used to generate both positive and negative ions for subsequent ion/ion reaction experiments. Ion/ion reactions took place after ions of each polarity were sequentially injected into a linear ion trap, where axial trapping
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