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线性分子式:
CH3C[=NSi(CH3)3]OSi(CH3)3
化学文摘社编号:
分子量:
203.43
UNSPSC Code:
41116105
NACRES:
NA.22
PubChem Substance ID:
EC Number:
233-892-7
Beilstein/REAXYS Number:
1306669
MDL number:
产品名称
N,O-双(三甲基甲硅烷基)乙酰胺, derivatization grade (GC derivatization), LiChropur™, ≥98.5% (GC)
InChI key
SIOVKLKJSOKLIF-CMDGGOBGSA-N
InChI
1S/C8H21NOSi2/c1-8(9-11(2,3)4)10-12(5,6)7/h1-7H3/b9-8+
SMILES string
C\C(O[Si](C)(C)C)=N/[Si](C)(C)C
grade
derivatization grade (GC derivatization)
assay
≥98.5% (GC)
form
liquid
quality
LiChropur™
reaction suitability
reagent type: derivatization reagent
reaction type: Silylations
technique(s)
gas chromatography (GC): suitable
refractive index
n20/D 1.417 (lit.)
n20/D 1.417
bp
71-73 °C/35 mmHg (lit.)
density
0.832 g/mL at 20 °C (lit.)
Quality Level
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Application
更多信息请参见产品信息
适用于衍生化 2-氨基-2-脱氧己糖、蜕皮素、己糖胺,这些成分分布在糖胺聚糖、18-羟皮质类固醇、15-脱氧-前列腺素 F2α、 前列腺素 A、B 和 E 和 F、F2α,前列腺素和代谢产物、前列腺素类代谢物、糖磷酸盐、类固醇和睾酮中。
General description
双(三甲基硅基)乙酰胺是一种优良的硅烷化试剂。对于某些空间位阻的伯、仲硝基化合物,N,O-双(三甲基硅基)乙酰胺和 BSTFA 能比正常的硅烷化条件获得更好的结果。
Other Notes
用于 o-三甲基硅烷基醛基-1,4-内酯、三甲基硅烷基和三甲基硅烷基醚的试剂。
高效硅烷化试剂
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
111.2 °F - closed cup
flash_point_c
44 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
K. Blau et al.
Handbook of Derivatives for Chromatography (1993)
J. Heberle et al.
Silylating Agents, 2nd ed. (1995)
Houben-Weyl Methods of Molecular Transformations. Heteroatom Analogues of Aldehydes and Ketones.
Aggarwal VK
Science of Synthesis Knowledge Updates, 27, 593-594 (2014)
Analysis of the prostaglandins E by glass capillary gas chromatography with electron capture detection.
M Korteweg et al.
Prostaglandins, 13(6), 1221-1223 (1977-06-01)
Anna Hjelm et al.
Applied and environmental microbiology, 81(2), 726-735 (2014-11-16)
Bacterial ghosts are empty cell envelopes of Gram-negative bacteria that can be used as vehicles for antigen delivery. Ghosts are generated by releasing the bacterial cytoplasmic contents through a channel in the cell envelope that is created by the controlled
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