15269
N,O-双(三甲基甲硅烷基)乙酰胺
derivatization grade (GC derivatization), LiChropur™, ≥98.5% (GC)
别名:
BSA
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线性分子式:
CH3C[=NSi(CH3)3]OSi(CH3)3
化学文摘社编号:
分子量:
203.43
UNSPSC Code:
41116105
NACRES:
NA.22
PubChem Substance ID:
EC Number:
233-892-7
Beilstein/REAXYS Number:
1306669
MDL number:
产品名称
N,O-双(三甲基甲硅烷基)乙酰胺, derivatization grade (GC derivatization), LiChropur™, ≥98.5% (GC)
InChI key
SIOVKLKJSOKLIF-CMDGGOBGSA-N
InChI
1S/C8H21NOSi2/c1-8(9-11(2,3)4)10-12(5,6)7/h1-7H3/b9-8+
SMILES string
C\C(O[Si](C)(C)C)=N/[Si](C)(C)C
grade
derivatization grade (GC derivatization)
assay
≥98.5% (GC)
form
liquid
quality
LiChropur™
reaction suitability
reagent type: derivatization reagent
reaction type: Silylations
technique(s)
gas chromatography (GC): suitable
refractive index
n20/D 1.417 (lit.)
n20/D 1.417
bp
71-73 °C/35 mmHg (lit.)
density
0.832 g/mL at 20 °C (lit.)
Quality Level
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Application
更多信息请参见产品信息
适用于衍生化 2-氨基-2-脱氧己糖、蜕皮素、己糖胺，这些成分分布在糖胺聚糖、18-羟皮质类固醇、15-脱氧-前列腺素 F2α、 前列腺素 A、B 和 E 和 F、F2α，前列腺素和代谢产物、前列腺素类代谢物、糖磷酸盐、类固醇和睾酮中。
General description
双（三甲基硅基）乙酰胺是一种优良的硅烷化试剂。对于某些空间位阻的伯、仲硝基化合物，N，O-双（三甲基硅基）乙酰胺和 BSTFA 能比正常的硅烷化条件获得更好的结果。
Other Notes
用于 o-三甲基硅烷基醛基-1,4-内酯、三甲基硅烷基和三甲基硅烷基醚的试剂。
高效硅烷化试剂
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
111.2 °F - closed cup
flash_point_c
44 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Houben-Weyl Methods of Molecular Transformations. Heteroatom Analogues of Aldehydes and Ketones.
Aggarwal VK
Science of Synthesis Knowledge Updates, 27, 593-594 (2014)
Analysis of the prostaglandins E by glass capillary gas chromatography with electron capture detection.
M Korteweg et al.
Prostaglandins, 13(6), 1221-1223 (1977-06-01)
J. Heberle et al.
Silylating Agents, 2nd ed. (1995)
K. Blau et al.
Handbook of Derivatives for Chromatography (1993)
Anna Hjelm et al.
Applied and environmental microbiology, 81(2), 726-735 (2014-11-16)
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