157775
五氯化磷
reagent grade, 95%
别名:
氯化磷(V)
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关于此项目
线性分子式:
PCl5
化学文摘社编号:
分子量:
208.24
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.21
等级
reagent grade
质量水平
蒸汽压
<1 mmHg ( 20 °C)
方案
95%
表单
powder
pH值（酸碱度）
1 (5 g/L)
mp
179-181 °C (subl.) (lit.)
SMILES字符串
ClP(Cl)(Cl)(Cl)Cl
InChI
1S/Cl5P/c1-6(2,3,4)5
InChI key
UHZYTMXLRWXGPK-UHFFFAOYSA-N
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一般描述
Phosphorus pentachloride is a light yellow colored phosphorous halide. It participates in the synthesis of thiazoline analogs.
应用
Phosphorus pentachloride may be used in the synthesis of following compounds:
Phosphorus pentachloride may be used as halogenating reagent to convert any substituted aldehyde into the corresponding vinyl halide. It can also undergo reaction with ammonium chloride to yield linear phosphazenes and cyclophosphazenes.
- benzenesulfonyl chloride
- malonic dinitrile
- aromatic sulfonyl chlorides
Phosphorus pentachloride may be used as halogenating reagent to convert any substituted aldehyde into the corresponding vinyl halide. It can also undergo reaction with ammonium chloride to yield linear phosphazenes and cyclophosphazenes.
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Inhalation
靶器官
Respiratory Tract
补充剂危害
储存分类代码
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 1
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Ley.VS
Comprehensive Organic Functional Group Transformations II, 2 (1995)
Allcock H
Phosphorus-Nitrogen Compounds: Cyclic, Linear, and High Polymeric Systems (2012)
Ley.VS et al.
Comprehensive Organic Functional Group Transformations: Synthesis: carbon with two heteroatoms, each attached by a single bond (2005)
Synthetic studies of thiazoline and thiazolidine-containing natural products-1. Phosphorus pentachloride-mediated thiazoline construction reaction.
Ino A and Murabayashi A.
Tetrahedron, 55(34), 10271-10282 (1999)
Eagleson M.
Concise Encyclopedia Chemistry, 617-617 (1994)
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