178780
四丁基氢氧化铵 溶液
40 wt. % in H₂O, solution
别名:
N,N,N-Tributyl-1-butanaminium hydroxide, TBAH 40, Tetra-n-butylammonium hydroxide
产品名称
四丁基氢氧化铵 溶液, 40 wt. % in H2O
表单
liquid
质量水平
环保替代产品特性
Catalysis
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浓度
40 wt. % in H2O
折射率
n20/D 1.405
密度
0.99 g/mL at 25 °C
官能团
amine
环保替代产品分类
SMILES字符串
[OH-].CCCC[N+](CCCC)(CCCC)CCCC
InChI
1S/C16H36N.H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H2/q+1;/p-1
InChI key
VDZOOKBUILJEDG-UHFFFAOYSA-M
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一般描述
四丁基氢氧化铵是一种季铵盐，主要用作强碱和相转移催化剂。它可以使用四丁基碘化铵合成。
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应用
四丁基氢氧化铵溶液（TBAOH）可用于以下研究：
- 在室温条件下溶解10％的纤维素。
- 作为合成1,2,4-恶二唑的催化剂。
- 制备脂肪酸的TBAOH盐。
免责声明
在30°C以下可能会结晶
温度升高和涡旋会使固体重新溶解
温度升高和涡旋会使固体重新溶解
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1
储存分类代码
8B - Non-combustible corrosive hazardous materials
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Tetrabutylammonium Hydroxide
Bos ME.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
Construction of 3, 5-substituted 1, 2, 4-oxadiazole rings triggered by tetrabutylammonium hydroxide: a highly efficient and fluoride-free ring closure reaction of O-acylamidoximes.
Otaka H, et al.
Tetrahedron Letters, 55(5), 979-981 (2014)
B B Y Lau et al.
Bioresource technology, 197, 252-259 (2015-09-08)
Aqueous solutions of tetrabutylphosphonium hydroxide have been evaluated as pretreatment media for rice husks, prior to sulphuric acid hydrolysis or cellulase enzymatic hydrolysis. Varying the water:tetrabutylphosphonium hydroxide ratio varied the rate of delignification, as well as silica, lignin and cellulose
Tetrabutylammonium Hydroxide as Titrant for Acids in Nonaqueous Solutions.
Cundiff RH and Markunas PC.
Analytical Chemistry, 28(5), 792-797 (1956)
Foaming and emulsifying properties of fatty acids neutralized by tetrabutylammonium hydroxide.
Fameau AL, et al.
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 403, 87-95 (2012)
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