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Merck
CN

194832

双硫腙

ACS reagent, ≥85.0%

别名:

二苯基硫卡巴腙

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线性分子式:
C6H5NHNHCSN=NC6H5
化学文摘社编号:
分子量:
256.33
EC Number:
200-454-1
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
748838
MDL number:
Assay:
≥85.0%
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InChI key

UOFGSWVZMUXXIY-BMRADRMJSA-N

InChI

1S/C13H12N4S/c18-13(16-14-11-7-3-1-4-8-11)17-15-12-9-5-2-6-10-12/h1-10,14H,(H,16,18)/b17-15+

SMILES string

S=C(NNc1ccccc1)\N=N\c2ccccc2

grade

ACS reagent

assay

≥85.0%

ign. residue

≤0.3%

mp

168 °C (dec.) (lit.)

cation traces

heavy metals: ≤0.002%

absorbance ratio

A ≥1.55

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General description

Dithizone (Diphenylthiocarbazone) is used as chelating agent for zinc. It is widely used for the liquid-liquid and solid phase extraction of various metals since it forms stable complexes with the metals.

Application

金属指示剂。
Dithizone (Diphenylthiocarbazone) may be used in the following studies:
  • In the cloud point preconcentration step, before the trace level quantification of silver by flame atomic absorption spectrometry.
  • Preparation of hexadecyltrimethyl ammonium bromide (CTAB) capped gold nanoparticles (AuNPs). This reagent was useful for the colorimetric detection of heavy metal ions.
  • As a zinc chelating ligand for the extraction of zinc in bovine serum.
Dithizone has been used in the preparation of dithizone stain solution for pancreatic islet cells.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Sonic hedgehog inhibition induces mouse embryonic stem cells to differentiate toward definitive endoderm.
Ghanbari A, et al.
Indian Journal of Experimental Biology, 51, 201-207 (2013)
Wei Yue et al.
Electroanalysis, 25(10), 2259-2267 (2014-01-18)
Metal catalyst free carbon nanotube (MCFCNT) whiskers were first used as an electrode modification material on a gold electrode surface for zinc voltammetric measurements. A composite film of Nafion and MCFCNT whiskers was applied to a gold electrode surface to
Yumin Leng et al.
Langmuir : the ACS journal of surfaces and colloids, 29(25), 7591-7599 (2013-06-04)
A new kind of analytical reagent, hexadecyl trimethyl ammonium bromide (CTAB), and dithizone product-modified gold nanoparticle dispersion, is developed for colorimetric response to 10 types of heavy metal ions (M(n+)), including Cr(VI), Cr(3+), Mn(2+), Co(2+), Ni(2+), Cu(2+), Zn(2+), Cd(2+), Hg(2+)
Analytica Chimica Acta, 57, 393-393 (1971)
Selective cloud point extraction and preconcentration of trace amounts of silver as a dithizone complex prior to flame atomic absorption spectrometric determination.
Manzoori JL and Karim-Nezhad G.
Analytica Chimica Acta, 484(2), 155-161 (2003)

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