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Merck
CN

20370

亚硝酸叔丁酯

technical, ≥90% (GC)

别名:

1,1-Dimethylethyl nitrite

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关于此项目

线性分子式:
(CH3)3CONO
化学文摘社编号:
分子量:
103.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-757-0
Beilstein/REAXYS Number:
1209339
MDL number:
Assay:
≥90% (GC)
Form:
liquid
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grade

technical

Quality Level

assay

≥90% (GC)

form

liquid

impurities

≤8% tert-butyl alcohol

refractive index

n20/D 1.368

bp

61-63 °C (lit.)

solubility

alcohol: very soluble, chloroform: very soluble, diethyl ether: very soluble, glycerol: insoluble, water: slightly soluble

density

0.864 g/mL at 20 °C, 0.867 g/mL at 25 °C (lit.)

functional group

O-nitroso, nitroso

storage temp.

2-8°C

SMILES string

CC(C)(C)ON=O

InChI

1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3

InChI key

IOGXOCVLYRDXLW-UHFFFAOYSA-N

General description

亚硝酸盐叔丁基是一种有机构件,广泛应用于各种有机转化,如氧化、重氮化、亚硝化、硝化、氧化、N-合成单体和其他反应。

Application

亚硝基叔丁酯可作为重氮合成芳基重氮盐的反应物。

Other Notes

用于亚硝化、动力学反应的试剂;近紫外光解生成 Me3C 自由基的清洁来源


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pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

14.0 °F - closed cup

flash_point_c

-10 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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L. Batt et al.
International Journal of Chemical Kinetics, 21, 535-535 (1989)
Brenden Kilpatrick et al.
Chemical communications (Cambridge, England), 49(5), 514-516 (2012-12-01)
A methodology for the efficient conversion of aromatic sulfonamides into their mono-nitro derivatives using tert-butyl nitrite is reported. The reaction exhibits a high degree of chemoselectivity for sulfonamide functionalized aryl systems, even in the presence of other sensitive or potentially
Quantum defects as versatile anchors for carbon nanotube functionalization
Mann F, et al.
Nature Protocols, 17, 727-747 (2022)



全球贸易项目编号

货号GTIN
20370-500ML-F04061836825683
20370-100ML-F04061838766229