grade
technical
Quality Level
assay
≥90% (GC)
form
liquid
impurities
≤8% tert-butyl alcohol
refractive index
n20/D 1.368
bp
61-63 °C (lit.)
solubility
alcohol: very soluble, chloroform: very soluble, diethyl ether: very soluble, glycerol: insoluble, water: slightly soluble
density
0.864 g/mL at 20 °C, 0.867 g/mL at 25 °C (lit.)
functional group
O-nitroso, nitroso
storage temp.
2-8°C
SMILES string
CC(C)(C)ON=O
InChI
1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3
InChI key
IOGXOCVLYRDXLW-UHFFFAOYSA-N
General description
亚硝酸盐叔丁基是一种有机构件,广泛应用于各种有机转化,如氧化、重氮化、亚硝化、硝化、氧化、N-合成单体和其他反应。
Application
亚硝基叔丁酯可作为重氮合成芳基重氮盐的反应物。
Other Notes
用于亚硝化、动力学反应的试剂;近紫外光解生成 Me3C 自由基的清洁来源
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
14.0 °F - closed cup
flash_point_c
-10 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
L. Batt et al.
International Journal of Chemical Kinetics, 21, 535-535 (1989)
Brenden Kilpatrick et al.
Chemical communications (Cambridge, England), 49(5), 514-516 (2012-12-01)
A methodology for the efficient conversion of aromatic sulfonamides into their mono-nitro derivatives using tert-butyl nitrite is reported. The reaction exhibits a high degree of chemoselectivity for sulfonamide functionalized aryl systems, even in the presence of other sensitive or potentially
Quantum defects as versatile anchors for carbon nanotube functionalization
Mann F, et al.
Nature Protocols, 17, 727-747 (2022)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 20370-500ML-F | 04061836825683 |
| 20370-100ML-F | 04061838766229 |

