20370
亚硝酸叔丁酯
technical, ≥90% (GC)
别名:
1,1-Dimethylethyl nitrite
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关于此项目
线性分子式:
(CH3)3CONO
化学文摘社编号:
分子量:
103.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-757-0
Beilstein/REAXYS Number:
1209339
MDL number:
Assay:
≥90% (GC)
Form:
liquid
grade
technical
Quality Level
assay
≥90% (GC)
form
liquid
impurities
≤8% tert-butyl alcohol
refractive index
n20/D 1.368
bp
61-63 °C (lit.)
solubility
alcohol: very soluble, chloroform: very soluble, diethyl ether: very soluble, glycerol: insoluble, water: slightly soluble
density
0.864 g/mL at 20 °C, 0.867 g/mL at 25 °C (lit.)
functional group
O-nitroso, nitroso
storage temp.
2-8°C
SMILES string
CC(C)(C)ON=O
InChI
1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3
InChI key
IOGXOCVLYRDXLW-UHFFFAOYSA-N
General description
亚硝酸盐叔丁基是一种有机构件，广泛应用于各种有机转化，如氧化、重氮化、亚硝化、硝化、氧化、N-合成单体和其他反应。
Application
亚硝基叔丁酯可作为重氮合成芳基重氮盐的反应物。
Other Notes
用于亚硝化、动力学反应的试剂；近紫外光解生成 Me3C 自由基的清洁来源
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
14.0 °F - closed cup
flash_point_c
-10 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
L. Batt et al.
International Journal of Chemical Kinetics, 21, 535-535 (1989)
M.J. Crookes et al.
J. Chem. Soc. Perkin Trans. II, 1339-1339 (1988)
tert-Butyl Nitrite (TBN), a Multitasking Reagent in Organic Synthesis
Dahiya A, et al.
Chemistry - An Asian Journal, 14, 4454-4492 (2019)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 20370-500ML-F | 04061836825683 |
| 20370-100ML-F | 04061838766229 |