21360
(+)-樟脑-10-磺酸
purum, ≥98.0% (T)
别名:
(+)-β-樟脑磺酸, (1S)-(+)-樟脑-10-磺酸
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关于此项目
经验公式（希尔记法）:
C10H16O4S
化学文摘社编号:
分子量:
232.30
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-554-1
Beilstein/REAXYS Number:
2809675
MDL number:
产品名称
(+)-樟脑-10-磺酸, purum, ≥98.0% (T)
InChI key
MIOPJNTWMNEORI-GMSGAONNSA-N
InChI
1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1
SMILES string
[H][C@@]12CC[C@@](CS(O)(=O)=O)(C(=O)C1)C2(C)C
grade
purum
assay
≥98.0% (T)
form
solid
optical activity
[α]20/D +21.5±1°, c = 10% in H2O
mp
~200 °C (dec.) (lit.)
functional group
ketone
sulfonic acid
Quality Level
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Application
（+） -樟脑-10-磺酸可作为合成10-碘樟脑的起始原料。(±)-S-甲基-S-苯基磺酰亚胺可作为手性拆分剂进行拆分，形成具有较高对映体纯度的 (-)-形式。掺杂 (+)-樟脑-10-磺酸的聚苯胺 (PAni) 形成导电聚合物纳米纤维，是优良的氨气传感器。
Other Notes
用于拆分碱的试剂；也可作为液相色谱分离的流动相添加剂；用于结晶诱导的不对称转化的试剂
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
A. Lore et al.
Journal of Liquid Chromatography, 14, 2065-2065 (1991)
P.J. Reider et al.
The Journal of Organic Chemistry, 52, 955-955 (1987)
T. Shiraiwa et al.
Bulletin of the Chemical Society of Japan, 64, 3729-3729 (1991)
C Pettersson et al.
Journal of chromatography, 204, 179-183 (1981-01-16)
A high-performance liquid chromatographic method for the separation of optical isomers (enantiomers) of amines is described. It is based on ion-pair chromatography with a chiral counter ion in a system with an organic mobile phase and an adsorbing stationary phase.
Electrospun polyaniline fibers as highly sensitive room temperature chemiresistive sensors for ammonia and nitrogen dioxide gases.
Zhang Y, et al.
Advances in Functional Materials, 24(25), 4005-4014 (2014)
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