22880
氯乙酰氯
purum, ≥99.0% (GC)
别名:
Chloroacetic chloride
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线性分子式:
ClCH2COCl
化学文摘社编号:
分子量:
112.94
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-171-6
Beilstein/REAXYS Number:
605439
MDL number:
Assay:
≥99.0% (GC)
Form:
liquid
vapor density
3.9 (vs air)
Quality Level
vapor pressure
60 mmHg ( 41.5 °C)
grade
purum
assay
≥99.0% (GC)
form
liquid
refractive index
n20/D 1.453
bp
105-106 °C (lit.)
mp
−22 °C (lit.)
solubility
water: insoluble
density
1.419 g/mL at 20 °C, 1.418 g/mL at 25 °C (lit.)
functional group
acyl chloride, chloro
SMILES string
ClCC(Cl)=O
InChI
1S/C2H2Cl2O/c3-1-2(4)5/h1H2
InChI key
VGCXGMAHQTYDJK-UHFFFAOYSA-N
General description
氯乙酰氯是一种脂肪族酰氯。
Application
氯乙酰氯可用于制备：
- 通过吡啶-2-胺的N-酰化作用制备2-氯-N-(吡啶-2-基)乙酰胺
- 通过 N,N-二甲基甲酰胺与纤维素反应，制备氯乙酰纤维素
- 在回流甲苯中存在碱的条件下，通过与1,3-苯并噻嗪反应制备苯并噻嗪类衍生物
- 通过与3,5-二芳基-4,5-二氢吡唑反应制备2-氯-1-(3,5-二芳基-4,5-二氢吡唑-1-基)-乙酮
- 在微波条件下，通过与氯代靛红反应，制备氯乙酰基
氯乙酰氯用于合成 N-肼基乙酰磺酰胺。
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Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1
target_organs
Lungs
supp_hazards
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
212.0 °F - closed cup
flash_point_c
100 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
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Oana Maria Parasca et al.
Revista medico-chirurgicala a Societatii de Medici si Naturalisti din Iasi, 117(1), 238-243 (2014-02-11)
Infections caused by bacterial species are common in immunocompromised patients and carry significant treatment costs and mortality. The emerging resistance of microorganisms to some synthetic antimicrobial agents makes it necessary to continue the research for new antimicrobial drugs. To design
Application of microwave induced Delepine reaction to the facile one pot synthesis of 7-substituted 1, 3-dihydro-2h-[1, 4]-benzodiazepin-2-one-5-methyl carboxylates from the corresponding 1-chloroacetyl isatins.
Sharma P, et al.
International Journal of Chemical Sciences, 8(1) (2010)
T F Dowsley et al.
Chemico-biological interactions, 95(3), 227-244 (1995-04-14)
1,1-Dichloroethylene (DCE) requires cytochrome P450-catalyzed bioactivation to electrophilic metabolites (1,1-dichloroethylene oxide, 2-chloroacetyl chloride and 2,2-dichloroacetaldehyde) to exert its cytotoxic effects. In this investigation, we examined the reactions of these metabolites with glutathione by spectroscopic and chromatographic techniques. In view of
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| PH000069-25MG | 04061831294842 |
| 22880-1L | 04061836691509 |
| 22880-100ML | 04061838781482 |
| 22880-500ML | 04061838781499 |