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经验公式(希尔记法):
C16H13ClO2
化学文摘社编号:
分子量:
272.73
MDL编号:
UNSPSC代码:
41115716
PubChem化学物质编号:
NACRES:
NA.22
等级
derivatization grade (chiral)
质量水平
产品线
ChiraSelect™
光学纯度
enantiomeric ratio: ≥99.0:1.0 (HPLC)
质量
LiChropur™
浓度
≥18 mM in acetone
技术
HPLC: suitable
折射率
n20/D 1.359
储存温度
2-8°C
SMILES字符串
ClC(=O)OC(C1c2c(cccc2)c3c1cccc3)C
InChI
1S/C16H13ClO2/c1-10(19-16(17)18)15-13-8-4-2-6-11(13)12-7-3-5-9-14(12)15/h2-10,15H,1H3
InChI key
SFRVOKMRHPQYGE-UHFFFAOYSA-N
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一般描述
(+)-1-(9-芴基)氯甲酸乙酯 [(+)-FLEC] 是一种手性衍生试剂。有助于分离 α 的对映体-氨基酸,以及有助于采用 HPLC 法测定其光学纯度。
应用
(+)-FLEC 可用于反相高效液相色谱-荧光检测系统的草铵膦对映选择性分析。
外形
溶液,5mg 溶于 1mL 丙酮中
法律信息
ChiraSelect is a trademark of Sigma-Aldrich Co. LLC
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
警示用语:
Danger
危险声明
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
靶器官
Central nervous system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
1.4 °F
闪点(°C)
-17 °C
法规信息
易制毒化学品(3类)
危险化学品
此项目有
Separation of enantiomers of a-hydroxy acids by reversed-phase liquid chromatography after derivatization with 1-(9-fluorenyl) ethyl chloroformate.
Fransson, Bengt, and Ulf Ragnarsson.
Journal of Chromatography A, 827, 31-36 (1998)
K C Chan et al.
Electrophoresis, 16(4), 504-509 (1995-04-01)
Direct enantiomeric separations of some racemic amino acids derivatized with 9-fluorenylmethyl chloroformate were obtained using cyclodextrin-modified micellar electrokinetic chromatography (CD/MEKC) with a buffer made up of 5 mM sodium borate (pH 9.2), 150 mM sodium dodecyl sulfate (SDS) and 40
M T Rosseel et al.
Journal of chromatography, 568(1), 239-245 (1991-07-17)
A sensitive high-performance liquid chromatographic method for the determination of the enantiomers of atenolol in rat plasma has been developed. Racemic atenolol and practolol (internal standard) were extracted from alkalinized plasma (pH 12) into dichloromethane containing 3% (v/v) heptafluoro-1-butanol, and
J Sukbuntherng et al.
Journal of analytical toxicology, 19(3), 139-147 (1995-05-01)
To study the disposition kinetics of methamphetamine (MAP), we have developed a sensitive high-performance liquid chromatographic (HPLC) assay to quantitate the enantiomers of MAP and its major metabolites, amphetamine (AP), p-hydroxymethamphetamine (p-OH-MAP), and p-hydroxyamphetamine (p-OH-AP), the latter two of which
Identifying the carboxy terminal amino acid of a protein.
T H Akiyama et al.
Methods in molecular biology (Clifton, N.J.), 64, 235-242 (1997-01-01)
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