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经验公式(希尔记法):
C15H11ClO2
化学文摘社编号:
分子量:
258.70
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
41115710
EC Number:
249-313-6
MDL number:
Beilstein/REAXYS Number:
2279177
产品名称
氯甲酸-9-芴基甲酯, derivatization grade (HPLC), LiChropur™, ≥99.0% (HPLC)
InChI key
IRXSLJNXXZKURP-UHFFFAOYSA-N
InChI
1S/C15H11ClO2/c16-15(17)18-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14H,9H2
SMILES string
ClC(=O)OCC1c2ccccc2-c3ccccc13
grade
derivatization grade (HPLC)
assay
≥99.0% (HPLC)
form
solid
quality
LiChropur™
technique(s)
HPLC: suitable
mp
61-64 °C
62-64 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
在氨基酸 HPLC 分析中,用于衍生化氨基酸;在固相肽合成中用于制备 N-Fmoc 氨基酸。
在采用HPLC进行分析时,Fmoc氯化物可在生物胺的柱前衍生化中,用作衍生化试剂。
General description
Fmoc氯化物是一种衍生剂。
Other Notes
在HPLC和荧光检测中,用作胺的柱前衍生化试剂(吸收波长:265 nm,发射波长:315 nm);用于毛细管电泳
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
J.V. Sancho et al.
Journal of Chromatography A, 678, 59-59 (1994)
K C Chan et al.
Journal of chromatography. A, 653(1), 93-97 (1993-10-29)
Laser-induced fluorescence (LIF) was applied to the detection of 9-fluorenylmethyl chloroformate (FMOC-Cl) derivatized amino acids separated by capillary electrophoresis. Fluorescence excitation was provided by a pulsed, KrF laser operating at 248 nm. A limit of detection of 5 x 10(-10)
J. Kirschbaum et al.
Journal of Chromatography A, 661, 193-193 (1994)
S. Einarsson et al.
Analytical Chemistry, 58, 1638-1638 (1986)
Bahareh Mohammadi et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 880(1), 12-18 (2011-12-17)
In High Performance Liquid Chromatographic (HPLC) determination of chemicals with acidic functions, different labeling agents are used to improve sensitivity of the assay. 9-Fluorenylmethyl chloroformate (FMOC-Cl), on the other hand, is a suitable labeling agent, which reacts with both primary
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