23186
氯甲酸-9-芴基甲酯
≥99.0%, for HPLC derivatization, LiChropur™
别名:
9-芴甲氧羰酰氯, Fmoc-Cl, 芴甲氧羰酰氯
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经验公式（希尔记法）:
C15H11ClO2
化学文摘社编号:
分子量:
258.70
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
41115710
EC Number:
249-313-6
MDL number:
Beilstein/REAXYS Number:
2279177
产品名称
氯甲酸-9-芴基甲酯, derivatization grade (HPLC), LiChropur™, ≥99.0% (HPLC)
InChI key
IRXSLJNXXZKURP-UHFFFAOYSA-N
InChI
1S/C15H11ClO2/c16-15(17)18-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14H,9H2
SMILES string
ClC(=O)OCC1c2ccccc2-c3ccccc13
grade
derivatization grade (HPLC)
assay
≥99.0% (HPLC)
form
solid
quality
LiChropur™
technique(s)
HPLC: suitable
mp
61-64 °C
62-64 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
在氨基酸 HPLC 分析中，用于衍生化氨基酸；在固相肽合成中用于制备 N-Fmoc 氨基酸。
在采用HPLC进行分析时，Fmoc氯化物可在生物胺的柱前衍生化中，用作衍生化试剂。
General description
Fmoc氯化物是一种衍生剂。
Other Notes
在HPLC和荧光检测中，用作胺的柱前衍生化试剂（吸收波长：265 nm，发射波长：315 nm）;用于毛细管电泳
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
J.V. Sancho et al.
Journal of Chromatography A, 678, 59-59 (1994)
K C Chan et al.
Journal of chromatography. A, 653(1), 93-97 (1993-10-29)
Laser-induced fluorescence (LIF) was applied to the detection of 9-fluorenylmethyl chloroformate (FMOC-Cl) derivatized amino acids separated by capillary electrophoresis. Fluorescence excitation was provided by a pulsed, KrF laser operating at 248 nm. A limit of detection of 5 x 10(-10)
J. Kirschbaum et al.
Journal of Chromatography A, 661, 193-193 (1994)
S. Einarsson et al.
Analytical Chemistry, 58, 1638-1638 (1986)
Ingrid Freuze et al.
Journal of chromatography. A, 1175(2), 197-206 (2007-11-21)
Experimental and theoretical influence of multivalent cations on the analysis of glyphosate and aminomethyl phosphonic acid (AMPA) was studied in pure water and in one surface water. The procedure chosen, based on derivatization with FMOC-Cl, HPLC separation, and fluorescence detection
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